Asian Journal of Research in Chemistry

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Some ionic conductivities in binary solvent mixtures: Ethylene Carbonate+ water mixtures


Affiliations
1 Department of Chemistry, Kishinchand Chellaram College, Dinshaw Wachha Road, Churchgate, Mumbai – 400020, India
     

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Ethylene Carbonate, (EC), has relatively high dipole moment and relative permittivity but its high freezing point (300C) has put several restriction on the use of EC directly as solvent for electrochemical studies. EC + water mixtures are more convenient for particular utilization, as they are miscible at various proportions (Viz 20, 40, 60 and 80 mass% EC + Water) at 250C with relative permittivity higher than that of water. With this background some conductance studies of monovalent salts were undertaken in these solvents. From the resulted limiting molar conductivity values the limiting ionic conductivity of some ions is reported in 20, 40, 60 and 80 weight% EC + Water at 250C.

Keywords

Ionic Conductivities, Binary Solvent Mixtures, Ec+ water
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Abstract Views: 319

PDF Views: 2




  • Some ionic conductivities in binary solvent mixtures: Ethylene Carbonate+ water mixtures

Abstract Views: 319  |  PDF Views: 2

Authors

Rajesh A. Samant
Department of Chemistry, Kishinchand Chellaram College, Dinshaw Wachha Road, Churchgate, Mumbai – 400020, India
Yogita M. Shinde
Department of Chemistry, Kishinchand Chellaram College, Dinshaw Wachha Road, Churchgate, Mumbai – 400020, India

Abstract


Ethylene Carbonate, (EC), has relatively high dipole moment and relative permittivity but its high freezing point (300C) has put several restriction on the use of EC directly as solvent for electrochemical studies. EC + water mixtures are more convenient for particular utilization, as they are miscible at various proportions (Viz 20, 40, 60 and 80 mass% EC + Water) at 250C with relative permittivity higher than that of water. With this background some conductance studies of monovalent salts were undertaken in these solvents. From the resulted limiting molar conductivity values the limiting ionic conductivity of some ions is reported in 20, 40, 60 and 80 weight% EC + Water at 250C.

Keywords


Ionic Conductivities, Binary Solvent Mixtures, Ec+ water

References