Asian Journal of Research in Chemistry

Open Access Open Access  Restricted Access Subscription Access
Open Access Open Access Open Access  Restricted Access Restricted Access Subscription Access

Cu (II) Ion Sorption by Way of Redox Polymers on the Basis of Polyamines and Tetrachloro-p-Benzoquinone


Affiliations
1 ISC Institute of Chemical Sciences Named after A.B. Bekturov, 106, Sh. Ualichanov Str., 050010 Almaty, Republic of Kazakhstan
     

   Subscribe/Renew Journal


The synthesis, structure and properties of aminoquinoid redox polymers have been developed and studied on the basis of polyamines and tetrachloro-p-benzoquinone. Cu (II) ion sorption by way of synthesized polymers depending on the concentration of metal and pH solution, the time of contact and the nature of initial polyamine has been studied. Comparative analysis has been carried out in relation to the indicators of sorption by industrial ion-exchange resins and synthesized samples.

Keywords

Redox Polymer, Polarography, Sorption, Heavy Metals, Green (sustainable) Chemistry
Subscription Login to verify subscription
User
Notifications
Font Size


  • Zhdanova AV, Vjalyh EA. Izvlechenie ionov tjazhelyh metallov iz vodnyh rastvorov guminovymi kislotami. Voda: himija i jekologija. 2; 2012: 3-10 (in Russ.).

  • Vigdergauz VE, Marchenkova T.G, Kunilova I.V. Sorbcionnoe koncentrirovanie rastvorov vyshhelachivanija hvostov obogashhenija mednocinkovyh rud. Cvetnye metally. 3; 2001: 21-23 (in Russ.).

  • Zemskova LA, Sheveleva IV, Vojt AV, Emelina TB, Glushhenko VJu. Sorbcija i jelektrosorbcija Cu (II) modificirovannymi uglevodorodnymi sorbentami. Cvetnye metally .2; 2007:57-60 (in Russ.).

  • Garber MI. Resursosberegajushhaja tehnologija gal'vanicheskih pokrytij. M.: Mashinostroenie, 1988 (in Russ.).

  • Cassidy HJ, Kun KA. Oxidation-reduction polymers. Chimia, Leningrad.1967 (in Russ.).

  • Ergozhin EE, Hirotsu T, Mukhitdinova BA, Polimbetova GS, Borangazieva AK. Redoxpolymers in the process of neutralization and utilization of phosphorous hydrogen. 40th IUAC Congress “Innovation in chemistry”, Beijin. 2005: 516.

  • Manecke G. Oxidation-redaction polymers. Pure and Appl. Chem. 38 (1-2); 1974:181-198.

  • Ergozhin EE, Mukhitdinova BA. Redoxionites. Nauka, Alma- Ata.1983 (in Russ.).

  • Zhuk DS, Gembizkii PA, Kargin VA. Polyethyleneimine. Moscow. 1971 (in Russ.).

  • Anastas PT, Warner J.C. Green Chemistry: Theory and Practice, Oxford University Press, New York.1998.

  • Cook S. Green chemistry – evolution or revolution? Green Chemistry. 1 (5); 1999: G138-G140.

  • Lebedev KB, Kazancev EI, Rozmanov VM, Paholkov VS, Chemezov VA. Ionity v cvetnoj metallurgii. Metallurgija.Moscow.1975 (in Russ.).

  • Chelnakova PN, Kolodonnyj VA. Selektivnoe izvlechenie kationov cvetnyh metallov iz stochnyh vod slaboosnovnymi anionitami. Zhurn.prikl.himii.77(1); 2004: 78-82 (in Russ.) .

  • Ergozhin EE, Chalov TK, Kovrigina TV, Iskakova RA, Nikitina AI. Issledovanie kompleksoobrazujushhej sposobnosti anionitov na osnove nekotoryh poliaminov, allil'nyh i jepoksidnyh soedinenij. Zhurn. Prikladnoj himii. 77(7); 2004: 1693-1698 (in Russ.).

  • Zhunusova GN, Nikitina AI, Shoinbekova SA, Muhitdinova BA, Ergozhin EE. Izuchenie sorbcii kationov tjazhelyh metallov i vanadat-ionov hlorsoderzhashhimi redoks-polimerami. Him.zhurn.Kazahstana. 4; 2006: 23-31(in Russ.)


Abstract Views: 352

PDF Views: 2




  • Cu (II) Ion Sorption by Way of Redox Polymers on the Basis of Polyamines and Tetrachloro-p-Benzoquinone

Abstract Views: 352  |  PDF Views: 2

Authors

B. A Mukhitdinova
ISC Institute of Chemical Sciences Named after A.B. Bekturov, 106, Sh. Ualichanov Str., 050010 Almaty, Republic of Kazakhstan
E.E. Ergozhin
ISC Institute of Chemical Sciences Named after A.B. Bekturov, 106, Sh. Ualichanov Str., 050010 Almaty, Republic of Kazakhstan
A I Nikitina
ISC Institute of Chemical Sciences Named after A.B. Bekturov, 106, Sh. Ualichanov Str., 050010 Almaty, Republic of Kazakhstan
T. K. Chalov
ISC Institute of Chemical Sciences Named after A.B. Bekturov, 106, Sh. Ualichanov Str., 050010 Almaty, Republic of Kazakhstan
T.V. Kovrigina
ISC Institute of Chemical Sciences Named after A.B. Bekturov, 106, Sh. Ualichanov Str., 050010 Almaty, Republic of Kazakhstan
A.T. Tasmagambet
ISC Institute of Chemical Sciences Named after A.B. Bekturov, 106, Sh. Ualichanov Str., 050010 Almaty, Republic of Kazakhstan
K. K. Ismailova
ISC Institute of Chemical Sciences Named after A.B. Bekturov, 106, Sh. Ualichanov Str., 050010 Almaty, Republic of Kazakhstan

Abstract


The synthesis, structure and properties of aminoquinoid redox polymers have been developed and studied on the basis of polyamines and tetrachloro-p-benzoquinone. Cu (II) ion sorption by way of synthesized polymers depending on the concentration of metal and pH solution, the time of contact and the nature of initial polyamine has been studied. Comparative analysis has been carried out in relation to the indicators of sorption by industrial ion-exchange resins and synthesized samples.

Keywords


Redox Polymer, Polarography, Sorption, Heavy Metals, Green (sustainable) Chemistry

References