Asian Journal of Research in Chemistry

Open Access Open Access  Restricted Access Subscription Access
Open Access Open Access Open Access  Restricted Access Restricted Access Subscription Access

Preparation and spectroscopic studies of charge-transfer complexes of 2, 2-bipyridine and hydroxy benzo pyridine as electron donors with chloranilic acid, 3, 5 di nitro benzoic acid and p-nitro phenol as electron acceptors in methanol


Affiliations
1 Department of Chemistry, Aligarh Muslim University, Aligarh
     

   Subscribe/Renew Journal


The reactions between 2,2 bipyridine (Bpy) and hydroxy benzo pyridine (8HQ) as electron donors with some acceptors such as chloranilic acid (CAA), 3, 5 di nitro benzoic acid (DNBA) and p-nitro phenol (PNP) were studied at room temperature. Based on FT- IR spectrum of the solid CT complexes along with the UV- visible spectroscopy for the reactions, the data obtained indicate the formation of 1:1 charge-transfer complexes. The infrared and 1H NMR spectroscopic data and XRD spectrum indicate a charge-transfer interaction associated with a proton migration from the acceptor to the donor followed by intermolecular hydrogen bonding

Keywords

Charge- Transfer Complexes, 2, 2 Bipyridine, Hydroxy Benzo Pyridine, FT- IR, UV- Visible, 1H NMR, XRD
Subscription Login to verify subscription
User
Notifications
Font Size


  • G. Briegleb, Electronen-donator Accepror Komplexe. Springer, Berlin (1961).

  • F. Gutmann and L. E. Lyons, Organic Semiconductors. Wiley, New York (1965).

  • R. M. Issa et al., Rev. Roum. Chim. X (5), 667 (1981).

  • U. C. Singh et al.. Spectrochim. Acta 37A (7), 505 (1981).

  • R. D. Srivastava, Y. S. Misra and P. N. Tripathi, Electrochim. Acta 27, 863 (1982)

  • S.M. Teleb, A.S. Gaballa, Spectrochim. Acta 62 (2005) 140– 145.

  • Y. Imai, K. Kamon, T. Kinuta, T. Sato, N. Tajima, R. Kuroda, Y. Matsubara, Eur. J. Org. Chem. 2009 (2009) 2519.

  • Y. Imai, K. Kamon, S. Kido, T. Sato, N. Tajima, R. Kuroda, Y. Matsubara, Eur. J. Org. Chem. 2008 (2008) 4784.

  • H. Kusama, H. Sugihara, J. Photochem. Photobiol. A 181 (2006) 268.

  • F. Gutmann, C. Johnson, H. Keyzer, J. Moln´ar, Charge-Transfer Complexes in Biochemical Systems, Marcel Dekker Inc., 1997.

  • R. Foster, Organic Charge-Transfer Complexes, Academic Press, London, New York, 1969.

  • R.S. Mulliken, W.B. Person, Molecular Complexes, Wiley/ Interscience, New York, 1969

  • Egan, T. J., Ross, D. C., and Adams, P. A. (1994). FEBS Lett., 352, 54.

  • Desai, P. K., Desai, P., Machhi, D., Desai, C. M., and Patel, D. (1996). Indian J. Chem., 35B, 871.

  • Hirano, Y., Uehara, M., Saeki, K., Kato, T., Takahashi, K., and Mizutani, T. (2002). J. Health Sci., 48, 118.

  • De Souza, M. V. N., and Vasconcelos, T. R. A. (2005). Quim, Nova, 28, 678.

  • [Voronin, V. G., Petrova, I. D., and Leksin, N. N. (1976). Pharmaceutical Chemistry Journal, 10(9), 1215.

  • Moorthy, P. N., Naik, D. B., Dwibedy, P., Dey, G. R., and Kishore, K. (1998). J. Phys. Chem. A, 102, 684.

  • R. Abou-Ettah, A. El-Korashy, J. Phys. Chem. 76 (1972) 2405.

  • Das, S.K.; Krishnamoorthy, G.; Dofra, S.K. Can. J. Chem. 2000, 78, 191.

  • R.D. Kross, V.A. Fassel, J. Am. Chem. Soc. 79 (1957) 38.

  • L.J. Bellamy, the Infrared Spectra of Complex Molecules, Chapman and Hall, London, 1975

  • Jones, G.; Jimenez, J.A.C. Tetrahedron Lett. 1999, 40, 8551.

  • Smith, G.; Bott, R.C.; Rae, A.D.; Willis, A.C. Aust. J. Chem. 2000, 53, 531.

  • Zhao Y, Zhang Z and Dang H 2003 J. Mater. Sci. Engg. A 359 405

  • M. Hasani, R. Alireza, Spectrochim. Acta A 65 (2006) 1093– 1097.

  • S. Bhattacharya, K. Gosh, C. Subrata, B. Momas, Spectrochim. Acta A 65 (2006) 659.

  • Smith, G.; Bott, R.C.; Rae, A.D.; Willis, A.C. Aust. J. Chem. 2000, 53, 531.


Abstract Views: 353

PDF Views: 2




  • Preparation and spectroscopic studies of charge-transfer complexes of 2, 2-bipyridine and hydroxy benzo pyridine as electron donors with chloranilic acid, 3, 5 di nitro benzoic acid and p-nitro phenol as electron acceptors in methanol

Abstract Views: 353  |  PDF Views: 2

Authors

Afaq Ahmad
Department of Chemistry, Aligarh Muslim University, Aligarh
Abdulsatar Abduljabbar Rzokee
Department of Chemistry, Aligarh Muslim University, Aligarh

Abstract


The reactions between 2,2 bipyridine (Bpy) and hydroxy benzo pyridine (8HQ) as electron donors with some acceptors such as chloranilic acid (CAA), 3, 5 di nitro benzoic acid (DNBA) and p-nitro phenol (PNP) were studied at room temperature. Based on FT- IR spectrum of the solid CT complexes along with the UV- visible spectroscopy for the reactions, the data obtained indicate the formation of 1:1 charge-transfer complexes. The infrared and 1H NMR spectroscopic data and XRD spectrum indicate a charge-transfer interaction associated with a proton migration from the acceptor to the donor followed by intermolecular hydrogen bonding

Keywords


Charge- Transfer Complexes, 2, 2 Bipyridine, Hydroxy Benzo Pyridine, FT- IR, UV- Visible, 1H NMR, XRD

References