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Comparison of Different Adsorption Equations in Describing Sulphate Adsorption before and after Removal of Organic Matter in Some Alfisols of Orissa


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1 Department of Soil Science and Agricultural Chemistry, Orissa University of Agriculture and Technology, Bhubaneswar (Orissa), India
     

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Efficiencies of Freundlich, Langmuir, Temkin and initial mass adsorption equations were compared to describe SO42- adsorption in four Alfisols of Orissa before and after removal of organic matter. There was increase in SO42- adsorption in all the soils after removal of organic matter. It was significant in the Suakati and Badbil soils containing more than 1% organic carbon. The initial mass adsorption equation was the best in describing SO42- adsorption both before and after removal of organic matter as evidenced by its highest average R2 and the lowest average SE values of all. The Freundlich equation was superior to the Langmuir and Temkin equations, whereas Temkin equation was superior to the Langmuir one in describing SO42- adsorption before and after removal of organic matter.

Keywords

Sulphate Adsorption, Freundlich, Langmuir, Temkin and Initial Mass Adsorption Equations.
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  • Comparison of Different Adsorption Equations in Describing Sulphate Adsorption before and after Removal of Organic Matter in Some Alfisols of Orissa

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Authors

P. K. Das
Department of Soil Science and Agricultural Chemistry, Orissa University of Agriculture and Technology, Bhubaneswar (Orissa), India
R. K. Nayak
Department of Soil Science and Agricultural Chemistry, Orissa University of Agriculture and Technology, Bhubaneswar (Orissa), India
S. K. Sahu
Department of Soil Science and Agricultural Chemistry, Orissa University of Agriculture and Technology, Bhubaneswar (Orissa), India

Abstract


Efficiencies of Freundlich, Langmuir, Temkin and initial mass adsorption equations were compared to describe SO42- adsorption in four Alfisols of Orissa before and after removal of organic matter. There was increase in SO42- adsorption in all the soils after removal of organic matter. It was significant in the Suakati and Badbil soils containing more than 1% organic carbon. The initial mass adsorption equation was the best in describing SO42- adsorption both before and after removal of organic matter as evidenced by its highest average R2 and the lowest average SE values of all. The Freundlich equation was superior to the Langmuir and Temkin equations, whereas Temkin equation was superior to the Langmuir one in describing SO42- adsorption before and after removal of organic matter.

Keywords


Sulphate Adsorption, Freundlich, Langmuir, Temkin and Initial Mass Adsorption Equations.