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Microstructuring by Two-Photon Polymerization using a Sub-Nanosecond Laser


Affiliations
1 Department of Physics, Indian Institute of Technology, Kanpur 208 016, India
 

A multi-photon absorption-based laser writing system with sub-micrometer resolution has been developed using an inexpensive sub-nanosecond laser for two- and three-dimensional structuring in photosensitive resist materials. New combinations of commercially available photoresists such as SU-8 and AR-N 4340, and a photo initiator (2, 4, diethyl-9H-thioxanten-9-one) with large two-photon absorption at 532 nm are shown to be effective in obtaining sub-micrometer line or dot resolution. Systematic studies of the resolution on the system and fabrication parameters such as laser power, writing speed, focusing arrangement, etc. have been carried out. The sub-nanosecond-based laser micro writer is an inexpensive alternative with similar capabilities as a femtosecond-based laser writer. This system is comparably effective and has much higher capabilities for 2D structuring in terms of the aspect ratio of the fabricated structures than conventional 2D laser micro writers.


Keywords

Fabrication Parameters, Photoresists, Subnanosecond Laser, Two-Photon Polymerization, Writing System.
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  • Lee, K.-S., Kim, R. H., Yang D.-Y. and Park, S. H., Advances in 3D nano/microfabrication using two-photon initiated polymerization. Prog. Polym. Sci., 2008, 33, 631–681.
  • Goswami, A., Phani, A., Umarji, A. M. and Madras, G., Polymer microfabrication by scanning based micro stereolithography: optical design and material functionality. Rev. Sci. Instrum., 2012, 83, 095003.
  • Kawata, S., Sun, H.-B., Tanaka, T. and Takada, K., Finer features for functional micro devices. Nature, 2001, 412, 697–698.
  • Emons, M., Obata, K., Binhammer, T., Ovsianikov, A., Chichkov, B. N. and Morgner, U., Two-photon polymerization technique with sub-50 nm resolution by sub-10 fs laser pulses. Opt. Mater. Express, 2012, 2, 942–947.
  • Reinhardt, C., Kiyan, R., Passinger, S., Stepanov, A. L., Ostendorf, A. and Chichkov, B. N., Rapid laser prototyping of plasmonic components. Appl. Phys. A, 2007, 89, 321–325.
  • Cumpston, B. H. et al., Two-photon polymerization initiators for three-dimensional optical data storage and microfabrication. Nature, 1999, 398, 51–54.
  • Farsari, M. and Chichkov, B. N., Materials processing: twophoton fabrication. Nature Photonics, 2009, 3, 450–452.
  • Schizas, C. et al., On the design and fabrication by two-photon polymerization of a readily assembled micro-valve. Int. J. Adv. Manuf. Technol., 2009, 48, 435–441.
  • Doraiswamy, A. et al., Two photon induced polymerization of organic inorganic hybrid biomaterials for microstructured medical devices. Acta Biomater., 2006, 2, 267–275.
  • He, G. S., Tan, L.-S., Zheng, Q. and Prasad, P. N., Multiphoton absorbing materials: molecular designs, characterizations and applications. Chem. Rev., 2008, 108, 1245–1330.
  • Chung, T.-T., Li Tseng, C., Hung, C.-P., Lin, C.-L. and Baldeck, P. L., Design and two-photon polymerization of complex functional micro-objects for lab-on-a-chip: rotating micro-valves. J. Neurosci. Neuroeng., 2013, 2, 1–5.
  • Malinauskas, M., Danilevicius, P. and Juodkazis, S., Threedimensional micro-/nano-structuring via direct write polymerization with picosecond laser pulses. Opt. Express, 2011, 19, 5602– 5610.
  • Malinauskas, M., Purlys, V., Rutkauskas, M. and Gadonas, R., Two-photon polymerization for fabrication of three-dimensional micro- and nanostructures over a large area. Proc. SPIE, 2009, 7204, 72040C–72040C-11.
  • Thiel, M., Fischer, J., von Freymann, G. and Wegener, M., Direct laser writing of three-dimensional submicron structures using a continuous-wave laser at 532 nm. Appl. Phys. Lett., 2010, 97, 221102.
  • del Campo, A. and Greiner, C., SU-8: a photoresist for highaspectratio and 3D submicron lithography. J. Micromech. Microeng., 2007, 17, R81–R95.
  • Cao, H.-Z., Zheng, M.-L., Zi Dong, X., Zhao, Z.-S. and Duan, X.-M., Direct writing of shape-controlled nanodot array by twophoton nanolithography using elliptical beam. Appl. Phys. Express, 2013, 6, 066501.
  • Boyd, R. W., Nonlinear Optics, Academic Press, Burlington, 2008, 3rd edn, pp. 556–558.
  • Leatherdale, C. A., DeVoe, R. J., Yeates, A. T., Belfield, K. D., Kajzar, F. and Lawson, C. M., SPIE Proc. Ser., 2003, 5211, 112– 123.
  • Liu, Y., Nolte, D. D. and Nolte, L. J. P., Large-format fabrication by two-photon polymerization in SU-8. Appl. Phys. A, 2010, 100, 181–191.

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  • Microstructuring by Two-Photon Polymerization using a Sub-Nanosecond Laser

Abstract Views: 496  |  PDF Views: 124

Authors

Raghwendra Kumar
Department of Physics, Indian Institute of Technology, Kanpur 208 016, India
S. Anantha Ramakrishna
Department of Physics, Indian Institute of Technology, Kanpur 208 016, India

Abstract


A multi-photon absorption-based laser writing system with sub-micrometer resolution has been developed using an inexpensive sub-nanosecond laser for two- and three-dimensional structuring in photosensitive resist materials. New combinations of commercially available photoresists such as SU-8 and AR-N 4340, and a photo initiator (2, 4, diethyl-9H-thioxanten-9-one) with large two-photon absorption at 532 nm are shown to be effective in obtaining sub-micrometer line or dot resolution. Systematic studies of the resolution on the system and fabrication parameters such as laser power, writing speed, focusing arrangement, etc. have been carried out. The sub-nanosecond-based laser micro writer is an inexpensive alternative with similar capabilities as a femtosecond-based laser writer. This system is comparably effective and has much higher capabilities for 2D structuring in terms of the aspect ratio of the fabricated structures than conventional 2D laser micro writers.


Keywords


Fabrication Parameters, Photoresists, Subnanosecond Laser, Two-Photon Polymerization, Writing System.

References





DOI: https://doi.org/10.18520/cs%2Fv112%2Fi08%2F1668-1674