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Fourth-Generation Refrigerant:HFO 1234yf


Affiliations
1 Material Science Division, Shriram Institute for Industrial Research, 19, University Road, Delhi 110 007, India
 

Refrigeration is a process to transfer heat from the objects for cooling and freezing for maintaining the temperature of surroundings for preservation purposes and comfort. Refrigerants are the materials to use in air-conditioning and refrigeration system. This article describes the developments and history of the first-, second-, third- and fourth-generation refrigerants. Moreover, the focus is on a fourth-generation refrigerant, viz. HFO-1234yf having zero ozone depletion potential and very low global warming potential. Synthesis procedure, chemistry, applications and consumption norms of HFO-1234yf are explained.

Keywords

Air-Conditioning and Refrigeration, Fourth-Generation Refrigerants, Global Warming Potential, Ozone Depleting Potential.
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  • Sahu, J. C. and Mandal, B. K.; http://www.coolingindia.in/blog/post/id/9952/recent-developments-in-alternative-refrigerants (accessed on 15 May 2016).

  • http://www.linde-gas.ro/internet.lg.lg.rou/ro/images/refrigerant_environmentalimpact_brochure_07_201254_80042.pdf?v=1.0 (accessed on 6 July 2016).

  • Verma, J. K., Satsangi, A. and Chaturani, V., A review of alternative to R134a (CH3CH2F) refrigerant. Int. J. Emerg. Technol. Adv. Eng., 2013, 3(1), 300-304.

  • Papasavva, S. and Moomaw, W., Comparison between HFC-134a and alternative refrigerants in mobile air conditioners using the GREEN-MAC-LCCP© model. In 15th International Refrigeration and Air Conditioning Conference, Purdue, USA, 2014, Paper 1475, pp. 1-10.

  • ASHRAE: Position Document on Refrigerants and their Responsible Use. 2012.

  • Venkatarathnam, G. and Murthy, S. S., Refrigerants for vapour compression refrigeration systems. Resonance, 2012, 17(2), 139-162.

  • Brown, S., Refrigerants and global climate change. In Engineering Colloquium, Godderd Space Flight Center, Maryland, 2010.

  • Nielsen, O. J., Javadi, M. S., Andersen, M. P. S., Hurley, M. D., Wallington, T. J. and Singh, R., Atmospheric chemistry of CF3CFCH2 : kinetics and mechanisms of gas-phase reactions with Cl atoms, OH radicals, and O3 . Chem. Phys. Lett., 2007, 439, 18-22.

  • Honeywell, Honeywell HF0-1234ze Blowing Agent, Honeywall Sales Specification, 2008; https://www51.honeywell.com/sm/lgwpfr/ common/documents/FP LGWP FR Honeywell-HFO-1234ze Literature document.pdf (accessed on 13 July 2016).

  • Nappa, M. J., Lousenberg, R. D. and Jackson, A., Synthesis of 1234YF by selective dehydrochlorination of 244bb. US 8263817 B2, 2012.

  • Nappa, M. J., Lousenberg, R. D. and Jackson, A., Synthesis of 1234yf by selective dehydrochlorination of 244bb. US 2012/ 0172638 A1, 2012.

  • Bektesevic, S., Tung, H. S., Wang, H., Merkel, D. C. and Johnson, R. C., Method for producing tetrafluoropropenes. US 2011/ 0270000 A1, 2011.

  • Wang, H. and Tung, H. S., Process for producing 2,3,3,3-tetrafluoropropene. WO 2013/049742 A1, 2013.

  • Wang, H. and Tung, H. S., Process for producing 2,3,3,3-tetrafluoropropene. US 9416074 B2, 2016.

  • Wang, H., Tung, H. S. and Daniel, C., Process for producing 2,3,3,3-tetrafluoropropene. US 2014/0350309, 2014.

  • Elsheikh, M. Y., Bonnet, P. and Chen, B. B., Process for the manufacture of tetrafluoroolefins. US 2013/0035526 A1, 2013.

  • Jackson, A., Lousenberg, R. D. and Nappa, M. J., Synthesis of 1234yf by selective dehydrochlorination of 244bb. WO 2012/ 006295 A1, 2012.

  • Sharratt, A. P., Low, R. E. and McCarthy, J. C., Process for preparing R-1234yf by base mediated dehydrohalogenation. US 8822740 B2, 2014.

  • Sharratt, A. P., Low, R. E. and McCarthy, J. C., Process for preparing R-1234yf by base mediated dehydrohalogenation. US 2013/ 0274528 A1, 2013.

  • Elsheikh, M. Y., Bonnet, P., Keeley, O. C. N. and Chen, B. B., Dehydrofluorination of pentafluoroalkanes to form tetrafluoroolefins. US 2013/0060069 A1, 2013.

  • Wendlinger, L., Bonnet, P., Pigamo, A. and Doucet, N., Process for the preparation of 2,3,3,3-tetrafluoropropene. US 2013/ 0267740 A1, 2013.

  • Yang, G. et al., Method for preparing 2,3,3,3-tetrafluoropropene. US 9,115,042 B2, 2015.

  • Yang, G. et al., Method for preparing 2,3,3,3-tetrafluoropropene. EP 2756883 A1, 2014.

  • Mukhopadhyay, S., Light, B. A., Fleming, K. M., Phillips, S. D. and Dubey, R. K., Gas phase synthesis of 2,3,3,3-tetrafluoro-1propene from 2-chloro-3,3,3-trifluoro-1-propene. US 2009/ 0124837 A1, 2009.

  • Johnson, R. C. and Merkel, D. C., Method for prolonging a catalyst’s life during hydrofluorination. US 2010/0331583 A1, 2010.

  • Bektesevic, S., Tung, H. S. and Wang, H., Process for producing 2,3,3,3-tetrafluoropropene. US 2014/0235904, 2014.

  • Kopkalli, H., Chiu, Y. and Tung, H. S., Method for producing fluorinated organic compounds. US 2011/0207974 A9, 2011.

  • Nose, M. and Komatsu, Y., Process for preparing 2,3,3,3-tetra-fluoropropene. US 8772554 B2, 2014.

  • Van Der Puy, M., Process for the preparation of 2,3,3,3-tetra-fluoropropene (HF0-1234yf). US 8071826 B2, 2011.

  • Cottrell, S. A., Chiu, Y., Kopkalli, H., Tung, H. S., Uhrich, K. D. and Scheidle, P., Methods of making 2,3,3,3-tetra-fluoro-2-propene. US 2012/0184785, 2012.

  • Nose, M. and Komatsu, Y., Process for preparing 2,3,3,3-tetra-fluoropropene. WO 2013/015068 A1, 2013.

  • Nappa, M. J., Mallikarjuna, V. N. and Slevert, A. C., Processes for producing 2,3,3,3-tetra-fluoropropene, a process for producing 1-chloro-2,3,3,3-penta-fluoropropane and azeotropic compositions of 1-chloro-2,3,3,3-tetra-fluoropropene with hf. US 2010/0076231 A1, 2010.

  • Devic, M., Guillet, D., Guiraud, E. and Wendlinger, L., Method for preparing 2,3,3,3-tetrafluoro-1-propene. US 2010/0305370 A1, 2010.

  • Seki, R., Okamoto, H., Takagi, H. and Kawaguchi, S., Process for producing 1,1-dichloro-2,3,3,3-tetrafluoropropene and 2,3,3,3- tetrafluoropropene, US 8642820 B2, 2014.

  • Rao, V. N. M. and Sievert, A. C., Process for producing 2,3,3,3tetrafluoropropene. US 2010/0022808 A1, 2010.

  • Takagi, H. and Okamoto, H., Process for producing 2,3,3,3-tetrafluoropropene. US 2011/0319679 A1, 2011.

  • Kawaguchi, S., Okamoto, H., Takeuchi, Y., Takagi, H., Watanabe, K. and Yanase, K., Process for producing 2,3,3,3-tetrafluoropropene. US 2011/0319680 A1, 2011.

  • Nappa, M. J., Compositions comprising 2,3,3,3-tetrafluoropropene, 1,1,2,3-tetra-chloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane. US 9051500 B2, 2015.

  • Wang, H. and Tung, H. S., Process for producing 2,3,3,3-tetrafluoropropene. US 2014/0303409 A1, 2014.

  • Yang, G., Method for preparing 2,3,3,3-tetrafluoropropene. US 9115042 B2, 2015.

  • Scott, B. F., Spencer, C., Scott, A. and Mabury, Muir, D. C. G., Poly and perfluorinated carboxylates in North American precipitation. Environ. Sci. Technol., 2006, 40, 7167-7174.

  • Berg, M., Muller, S. R., Muhlemann, J., Wiedmer, A. and Schwarzenbach, R. P., Concentrations and mass fluxes of chloroacetic acids and trifluoroacetic acid in rain and natural waters in Switzerland. Environ. Sci. Technol., 2000, 34, 2675-2683.

  • Frank, H., Christoph, E. H., Holm-Hansen, O. and Bullister, J. L., Trifluoroacetate in ocean waters. Environ. Sci. Technol., 2002, 36, 12-15.

  • Scott, B. F. et al., Trifluoroacetate profiles in the Arctic, Atlantic, and Pacific Oceans. Environ. Sci. Technol., 2005, 39, 6555-6560.

  • Von Sydow, L., Grimvall, A., Boren, H., Laniewski, K. and Nielsen, A., Natural background levels of trifluoroacetate in rain and snow. Environ. Sci. Technol., 2000, 34, 3115-3118.

  • Boutonnet, J. C. et al., Environmental risk assessment of trifluoroacetic acid. Hum. Ecol. Risk Assess., 1999, 5, 59-124.

  • Kim, B. R., Suidan, M. T., Wallington, T. J. and Du, X., Biodegradability of trifluoroacetic acid. Environ. Eng. Sci., 2009, 17(6), 337-342.

  • Tang, X., Madronich, S., Wallington, T. and Calamari, D., Changes in tropospheric composition and air quality. J. Photochem. Photobiol. B, 1998, 46(1-3), 83-95.

  • https://en.wikipedia.org/wiki/2,3,3,3-Tetrafluoropropene (accessed on 12 December 2015).

  • Brown, J. S., HFOs: new, low global warming potential refrigerants. ASHRAE J., 2009, 22-29.

  • Akasaka, R., Kayukawa, Y., Kano, Y. and Fujii, K., Fundamental equation of state for 2,3,3,3-tetrafluoropropene (HFO-1234yf). In International Symposium on Next-Gene ration Air Conditioning and Refrigeration Technology, New Energy and Industrial Technology Development Organization, Tokyo, Japan, 2010.

  • Brown, J. S., Zilio, C. and Cavallini, A., Critical review of the latest thermodynamic and transport property data and models, and equations of state for R-1234yf. In 13th International Refrigeration and Air Conditioning Conference, Purdue, USA, 2010, Paper 1130, pp. 1-9.

  • Cang, C., Saitoh, S., Nakamura, Y., Li, M. and Hihara, E., Boiling heat transfer of HFO-1234yf flowing in smooth small-diameter horizontal tube. In International Symposium on Next-Generation Air Conditioning and Refrigeration Technology, New Energy and Industrial Technology Development Organization, Tokyo, Japan, 2010.

  • Higashi, Y., Thermophysical properties of HFO-1234yf and HFO1234ze (E). In International Symposium on Next-Generation Air Conditioning and Refrigeration Technology, New Energy and Industrial Technology Development Organization, Tokyo, Japan, 2010.

  • McLinden, M. O., Thol, M. and Lemmon, E. W., Thermodynamic properties of trans-1,3,3,3-tetrafluoropropene [R 1234ze(e)]: measurements of density and vapor pressure and a comprehensive international equation of state. In 13th International Refrigeration and Air Conditioning Conference, Purdue, USA, 2010, pp. 1-8.

  • Reaser, P., Aute, V. and Radermacher, R., Refrigerant R1234yf performance comparison investigation. In International Refrigeration and Air Conditioning Conference, USA, Paper 1085, 2010, pp. 1-7.

  • Zhang, S. J., Wang, H. X. and Guo, T., Evaluation of nonazeotropic mixtures containing HFOs as potential refrigerants in refrigeration and high-temperature heat pump systems. Sci. China Technol Sci., 2010, 53, 1855-1861.

  • Esbri, J. N., Miranda, J. M. M., Babiloni, A. M., Cervera, A. B.and Flores, J. M. B., Experimental analysis of R1234yf as a dropin replacement for R134a in a vapor compression system. Int. J. Refrig., 2012, 36, 870-880.

  • Jung, D., Lee, Y. and Kang, D., Performance of virtually nonflammable azeotropic HFO1234yf/HFC134a mixture for HFC134a applications. Int. J. Refrig., 2013, 36, 1203-1207.

  • Araz, M., Gungor, A. and Hepbasli, A., Experimental exergetic performance evaluation of an elevator air conditioner using R-1234yf. IACSIT Int. J. Eng. Technol, 2015, 7(3), 254-260.

  • Minor, B. H. and Spatz, M., HFO-1234yf low GWP refrigerant update. In International Refrigeration and Air Conditioning Conference, Purdue, USA, 14-17 July 2008.

  • Ansari, N. A., Yadav, B. and Kumar, J., Theoretical exergy analysis of HFO-1234yf and HFO-1234ze as an alternative replacement of HFC-134a in simple vapour compression. Int. J. Sci. Eng. Res., 2013, 4(8), 137.

  • https://www.kth.se/en/itm/inst/energiteknik/forskning/ett/projekt/koldmedier-med-lag-gwp/low-gwp-news/stabilitet-och-kompatibilitetav-hfo-koldmedier-1.328321

  • Koban, M., HFO-1234yf low GWP refrigerant - a global sustainable solution for mobile air conditioning. In Vehicle Thermal Management Systems Conference and Exhibition, SAE International, Scottsdale, AZ, 2008, p. 108.

  • Minor, B. H., Herrmann, D. and Gravell, R., Flammability characteristics of HFO-1234yf. Process Saf. Prog., 2010, 29(2), 150154.

  • https://www.chemours.com/Refrigerants/en US/assets/downloads/SmartAutoAC/20100520 VDA press briefing.pdf (accessed on 15 August 2016).

  • http://media.gm.com/content/media/us/en/news/news detail.brand gm.html/content/Pages/news/us/en/2010/July/0723 refrigerant (accessed on 13 September 2016).


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  • Fourth-Generation Refrigerant:HFO 1234yf

Abstract Views: 321  |  PDF Views: 119

Authors

Pinklesh Arora
Material Science Division, Shriram Institute for Industrial Research, 19, University Road, Delhi 110 007, India
Geetha Seshadri
Material Science Division, Shriram Institute for Industrial Research, 19, University Road, Delhi 110 007, India
Ajay Kumar Tyagi
Material Science Division, Shriram Institute for Industrial Research, 19, University Road, Delhi 110 007, India

Abstract


Refrigeration is a process to transfer heat from the objects for cooling and freezing for maintaining the temperature of surroundings for preservation purposes and comfort. Refrigerants are the materials to use in air-conditioning and refrigeration system. This article describes the developments and history of the first-, second-, third- and fourth-generation refrigerants. Moreover, the focus is on a fourth-generation refrigerant, viz. HFO-1234yf having zero ozone depletion potential and very low global warming potential. Synthesis procedure, chemistry, applications and consumption norms of HFO-1234yf are explained.

Keywords


Air-Conditioning and Refrigeration, Fourth-Generation Refrigerants, Global Warming Potential, Ozone Depleting Potential.

References





DOI: https://doi.org/10.18520/cs%2Fv115%2Fi8%2F1497-1503