Open Access
Subscription Access
Characteristics of Aniline and Nitrobenzene Adsorption on Single-Walled, Multi-Walled and Graphitized Multi-Walled Carbon Nanotubes
Herein, we assess the relative potential of singlewalled, multi-walled and graphitized multi-walled carbon nanotubes (CNTs) for the adsorptive removal of organic species using aniline and nitrobenzene as model aromatic contaminants. The obtained results reveal that the adsorption behaviour of aromatic organics is significantly affected by their functional groups (especially when functionalized CNTs are used as adsorbent), providing valuable guidance for adsorption- based removal of organic contaminants from the environment.
Keywords
Adsorption, Aromatic Organics, Carbon Nanotubes, Relative Potential.
User
Font Size
Information
- Xu, P., Yu, B., Li, F. L., Cai, X. F. and Ma, C. Q., Microbial degradation of sulfur, nitrogen and oxygen heterocycles. Trends Microbiol., 2006, 14, 398–405.
- Bi, E., Schmidt, T. C. and Haderlein, S. B., Environmental factors influencing sorption of heterocyclic aromatic compounds to soil. Environ. Sci. Technol., 2007, 41, 3172–3178.
- Rouquerol, J., Rouquerol, F., Llewellyn, P., Maurin, G. and Sing, K. S., Adsorption by Powders and Porous Solids: Principles, Methodology and Applications, Academic Press, 2013.
- Sillanpaa, M. E., Kurniawan, T. A. and Lo, W. H., Degradation of chelating agents in aqueous solution using advanced oxidation process (AOP). Chemosphere, 2011, 83, 1443–1460.
- Takht Ravanchi, M., Kaghazchi, T. and Kargari, A., Application of membrane separation processes in petrochemical industry: a review. Desalination, 2009, 235, 199–244.
- Borukhova, S., Biomass for sustainable applications: pollution remediation and energy. Green Process. Synth., 2014, 3, 305–306.
- Abhishek, A., Saranya, N., Chandi, P. and Selvaraju, N., Studies on the remediation of chromium (vi) from simulated wastewater using novel biomass of Pinus kesiya cone. Desalin. Water Treat., 2018, 114, 192–204.
- Saranya, N., Department of Chemical Engineering, N.I.o.T.C., Calicut 673601, Kerala, India, Nakeeran, E., Department of Chemical Engineering, N.I.o.T.C., Calicut 673601, Kerala, India, Giri Nandagopal, M.S., Department of Chemical Engineering, N.I.o.T.C., Calicut 673601, Kerala, India, Selvaraju, N. and Department of Chemical Engineering, N.I.o.T.C., Calicut 673601, Kerala, India, Optimization of adsorption process parameters by response surface methodology for hexavalent chromium removal from aqueous solutions using annona reticulata linn peel microparticles. Water Sci. Technol., 2018, 75, 2094–2107.
- Nakkeeran, E., Patra, C., Shahnaz, T., Rangabhashiyam, S. and Selvaraju, N., Continuous biosorption assessment for the removal of hexavalent chromium from aqueous solutions using Strychnos nux-vomica fruit shell. Bioresour. Technol. Rep., 2018, 3, 256– 260.
- Karthik, V., Saravanan, K., Nakkeeran, E. and Selvaraju, N., Biosorption of turquoise blue dye from aqueous solution by dried fungal biomass (Trichoderma harzianum) – kinetic, isotherm and thermodynamic studies. Desalination Water Treatment, 2017, 74, 362–370.
- Demirbas, A., Agricultural based activated carbons for the removal of dyes from aqueous solutions: a review. J. Hazard. Mater., 2009, 167, 1–9.
- Hosseini, S. J., Kokhdan, S. N., Ghaedi, A. M. and Moosavian, S. S., Comparison of multiwalled carbon nanotubes and activated carbon for efficient removal of methyl orange: kinetic and thermodynamic investigation. Fresinius Environ. Bull., 2011, 20, 219– 234.
- Iijima, S., Helical microtubules of graphitic carbon. Nature, 1991, 354, 56–58.
- Brar, S. K., Verma, M., Tyagi, R. D. and Surampalli, R. Y., Engineered nanoparticles in wastewater and wastewater sludge – evidence and impacts. Waste Manage., 2010, 30, 504–520.
- Pyrzynska, K., Carbon nanostructures for separation, preconcentration and speciation of metal ions. TrAC-Trends Anal. Chem., 2010, 29, 718–727.
- Herrero Latorre, C., Alvarez Mendez, J., Barciela Garcia, J., Garcia Martin, S. and Pena Crecente, R. M., Carbon nanotubes as solid-phase extraction sorbents prior to atomic spectrometric determination of metal species: a review. Anal. Chim. Acta, 2012, 749, 16–35.
- Yu, J. G. et al., Aqueous adsorption and removal of organic contaminants by carbon nanotubes. Sci. Total Environ., 2014, 482– 483, 241–251.
- Apul, O. G. and Karanfil, T., Adsorption of synthetic organic contaminants by carbon nanotubes: a critical review. Water Res., 2015, 68, 34–55.
- Ncibi, M. C. and Sillanpaa, M., Optimized removal of antibiotic drugs from aqueous solutions using single, double and multi-walled carbon nanotubes. J. Hazard Mater., 2015, 298, 102– 110.
- Peng, X., Hu, F., Lam, F. L., Wang, Y., Liu, Z. and Dai, H., Adsorption behaviour and mechanisms of ciprofloxacin from aqueous solution by ordered mesoporous carbon and bamboobased carbon. J. Colloid Interface Sci., 2015, 460, 349–360.
- Upadhyayula, V. K., Deng, S., Mitchell, M. C. and Smith, G. B., Application of carbon nanotube technology for removal of contaminants in drinking water: a review. Sci. Total Environ., 2009, 408, 1–13.
- Balarak, D., Mostafapour, F., Bazrafshan, E. and Saleh, T. A., Studies on the adsorption of amoxicillin on multi-wall carbon nanotubes. Water Sci. Technol., 2017, 75, 1599–1606.
- Agarwal, S., Tyagi, I., Gupta, V. K., Dehghani, M. H., Jaafari, J., Balarak, D. and Asif, M., Rapid removal of noxious nickel (II) using novel γ -alumina nanoparticles and multiwalled carbon nanotubes: kinetic and isotherm studies. J. Mol. Liquids, 2016, 224, 618–623.
- Balarak, D., Mahdavi, Y., Bazrafshan, E., Mahvi, A. H. and Esfandyari, Y., Adsorption of fluoride from aqueous solutions by carbon nanotubes: determination of equilibrium, kinetic, and thermodynamic parameters. Adsorption, 2016.
- Ajayan, P., Nanotubes from carbon. Chem. Rev., 1999, 99, 1787– 1800.
- Bahgat, M., Farghali, A. A., El Rouby, W. M. A. and Khedr, M. H., Synthesis and modification of multi-walled carbon nano-tubes (mwcnts) for water treatment applications. J. Anal. Appl. Pyrol., 2011, 92, 307–313.
- Ma, X. M., Tsige, M., Uddin, S. and Talapatra, S., Application of carbon nanotubes for removing organic contaminants from water. Mater. Express, 2011, 1, 183–200.
- Ruelle, B., Peeterbroeck, S., Godfroid, T., Bittencourt, C., Hecq, M., Snyders, R. and Dubois, P., Selective grafting of primary amines onto carbon nanotubes via free-radical treatment in microwave plasma post-discharge. Polymers – Basel, 2012, 4, 296–315.
- Dong, L. Z. C., Discussion on the difference between single wall carbon nanotubes and multi walled carbon nanotubes. Friend Sci. Amateurs, 2012, 14–15.
- Terrones, M., Science and technology of the twenty-first century: synthesis, properties and applications of carbon nanotubes. Annu. Rev. Mater. Res., 2003, 33, 419–501.
- Zhao, J., Preparation and application of high quality multi walled carbon nanotubes, Shanghai Jiao Tong University, China.
- Bittner, E. W., Smith, M. R. and Bockrath, B. C., Characterization of the surfaces of single-walled carbon nanotubes using alcohols and hydrocarbons: a pulse adsorption technique. Carbon, 2003, 41, 1231–1239.
- Peng, X. J. J. and Luan, Z. K., Application of carbon nanotubes in the field of water treatment materials. Prog. Chem., 2009, 1987– 1992.
- Yang, K. and Xing, B., Adsorption of organic compounds by carbon nanomaterials in aqueous phase: polanyi theory and its application. Chem. Rev., 2010, 110, 5989–6008.
- Zhang, L. L. X. and Feng, J. W., The influence of graphitization on the structure and electrical properties of carbon nanotubes. J. Inorg. Mater., 2009, 535–538.
- Barrett, E. P., Joyner, L. G. and Halenda, P. P., The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. J. Am. Chem. Soc., 1951, 73, 373–380.
- Azarpira, H., Mahdavi, Y., Khaleghi, O. and Balarak, D., Thermodynamic studies on the removal of metronidazole antibiotic by multi-walled carbon nanotubes. Pharm. Lett., 2016, 8, 107–113.
- Balarak, D., Bazrafshan, E., Mahdavi, Y., Lalhmunsiama and Lee, S. M., Kinetic, isotherms and thermodynamic studies in the removal of 2-chlorophenol from aqueous solution using modified rice straw. Desalin. Water Treat., 2017, 63, 203–211.
- Mohammadi, L., Bazrafshan, E., Noroozifar, M., AnsariMoghaddam, A., Barahuie, F. and Balarak, D., Adsorptive removal of benzene and toluene from aqueous environments by cupric oxide nanoparticles: kinetics and isotherm studies. J. Chem., 2017, 2017.
- Padwa, A. and Pearson, W., The chemistry of heterocyclic compounds, synthetic applications of 1,3-dipolar cycloaddition chemistry toward heterocycles and natural products. John Wiley.
- Chen, W., Duan, L. and Zhu, D., Adsorption of polar and nonpolar organic chemicals to carbon nanotubes. Environ. Sci. Technol., 2007, 41, 8295–8300.
- Wu, W., Chen, W., Lin, D. and Yang, K., Influence of surface oxidation of multiwalled carbon nanotubes on the adsorption affinity and capacity of polar and nonpolar organic compounds in aqueous phase. Environ. Sci. Technol., 2012, 46, 5446–5454.
- Chen, W., Duan, L., Wang, L. and Zhu, D., Adsorption of hydroxyland amino-substituted aromatics to carbon nanotubes. Environ. Sci. Technol., 2008, 42, 6862–6868.
Abstract Views: 325
PDF Views: 114