Open Access Open Access  Restricted Access Subscription Access

Elemental Composition and Microstructure Analysis of Archaeological Copper from Central Ganga Valley, India


Affiliations
1 Department of History, Babasaheb Bhimrao Ambedkar University, Lucknow 226 025, India
 

Copper alloys from an early-historic period site Kausambi, Uttar Pradesh, India were studied to understand the manufacturing technology and alloying practices through elemental analysis and microstructural examination. Most of the analysed samples were tin bronzes, and microstructure examination demonstrated casting, forging and annealing procedures adopted in manufacturing. Arsenic was absent in most of the samples, which may be due to recycling of the metal and awareness regarding the health hazards of this element among artisans. It is suggested that arsenic was not intentionally mixed in archaeological copper. On the other hand, tin was added in different quantities to meet the desired physical properties of the end-products. It is reported that copper metallurgy was developed in due course of time as a specialized craft in the Central Gangetic Valley, India and artisans of this region had mastered the copper-alloy technology since the early historic period.

Keywords

Archaeometallurgy, Copper Alloys, Early Historic Period, Elemental Composition, Microstructure Analysis.
User
Notifications
Font Size

  • Chakrabarti, D. K., Archaeological Geography of the Ganga Plain: The Lower and the Middle Ganga, Permanent Black, New Delhi, 2001.
  • Lahiri, N., The Archaeology of Indian Trade Routes upto c. 200 BC: Resource Use, Resource Access and Line of Communication, Oxford University Press, New Delhi, 1992.
  • Chakrabarti, D. K., India – An Archaeological History (Palaeolithic Beginnings to Early Historic Foundations), Oxford University Press, New Delhi, 1999.
  • Chakrabarti, D. K. and Lahiri, N., Copper and its Alloys in Ancient India, Munshiram Manoharlal, New Delhi, 1996.
  • Biswas, A. K. and Biswas, S., Minerals and Metals in Ancient India: Archaeological Evidence (Vol. 1), D.K. Printworld, New Delhi, 1996.
  • Shrivastva, R., Mining of copper in Ancient India. Indian J. Hist. Sci., 1999, 34, 173–180.
  • Bhardwaj, H. C., Aspects of Ancient Indian Technology: A Research Based on Scientific Methods, Motilal Banarsidass, Delhi, 1979.
  • Singh, B. P., Early farming communities of Kaimur foot hills. Puratattva, 1990, 19, 6–18.
  • Singh, R. N., Aspects of archaeometallurgy in South and South– East Asia: A Study of Metal Objects from North India and Thailand, Kala Prakashan, Varanasi, 2007.
  • Singh, R. N. and Merkel, J. F., High-tin bronzes in middle Ganga Plain: some chemical considerations. In Paper Presented at the Fifth World Archaeological Congress, Washington, DC, USA, 2003.
  • Singh, A. K. and Chattopadhyay, P. K., Carinated and knobbed copper vessels from the Narhan Culture, India. IAMS, 2003, 23, 27–31.
  • Rai, S. S., Rai, G. K., Pandey, A. C. and Chattopadhyaya, U. C., Geochemical studies of the ancient Indian glazed ware. Curr. Sci., 2014, 106, 428–433.
  • Sharma, G. R., Excavations at Kausambi (1957–59): The Defences and the Syenaciti of the Purusamedha, Department of Ancient History, Culture and Archaeology, University of Allahabad, Allahabad, 1960.
  • Rhys Davids, T. W., Buddhist India Putnam, London, UK, 1903.
  • Tite, M. S., Archaeological science – past achievements and future prospects. Archaeometry, 1991, 33, 139–151.
  • Northover, P., Metallographic analysis. In Encyclopedia of Archaeology (ed. Pearsall, D. M.), Academic Press, New York, USA, 2008, pp. 1608–1613.
  • Scott, D. A. and Schwab, R., Metallography in Archaeology and Art, Springer International Publishing, Cham, Switzerland, 2019.
  • Louthan, M. R., Optical metallography. In ASM Handbook, Volume 10: Materials Characterizations (ed. Whan, R. E.), ASM International, New York, USA, 1986, pp. 299–308.
  • Aliya, D., Metallographic sectioning and specimen extraction. In Metallography and Microstructures (ed. Vander Voort, G. F.), ASM International, New York, USA, 2004, pp. 229–241.
  • Lifshin, E., Morris, W. G. and Bolon, R. B., The scanning electron microscope and its applications in metallurgy. JOM, 1969, 21, 43–50.
  • Stefanescu, D. M., Science and Engineering of Casting Solidification, Springer International Publishing, Cham, Switzerland, 2015.
  • Singh, R. N., Merkel, J. F. and Singh, A. K., SEM and EPMA analysis of copper objects from Narhan. Pragdhara, 1997, 7, 123– 129.
  • Hegde, K. T. M., Sources of ancient tin in India. In The Search for Ancient Tin (eds Franklin, A. D., Olin, J. S. and Wertime, T. A.), National Bureau of Standards, Washington, DC, USA, 1978, pp. 39–42.
  • Chakrabarti, D. K., The problem of tin in early India – a preliminary survey. Man Environ., 1979, 3, 61–74.
  • Davis, J. R., Copper and Copper Alloys, ASM International, Materials Park, OH, USA, 2001.
  • Chattopadhyay, P. K., Archaeometallurgical investigation on material technology of high-tin bronze between the early historic and pre-industrial periods of Bengal. Jadavpur University, Kolkata, 2012.
  • Scott, D. A., Podany, J. and Considine, B. B., Ancient and Historic Metals: Conservation and Scientific Research, Getty Publications, Marina del Rey, California, USA, 1994.
  • Srinivasan, S., Indian high-tin bronzes and the Grecian and Persian World. Indian J. Hist. Sci., 2016, 51, 601–612.
  • Srinivasan, S., Metallurgy of zinc, high-tin bronze and gold in Indian antiquity: methodological aspects. Indian J. Hist. Sci., 2016, 51, 22–32.
  • Mödlinger, M., de Oro Calderon, R. and Haubner, R., Arsenic loss during metallurgical processing of arsenical bronze. Archaeol. Anthropol. Sci., 2019, 11, 133–140.
  • Lechtman, H. and Klein, S., The production of copper–arsenic alloys (arsenic bronze) by cosmelting: modern experiment, ancient practice. J. Archaeol. Sci., 1999, 26, 497–526.
  • Yule, P., Hauptmann, A. and Hughes, M. J., The copper hoards of the Indian subcontinent. Preliminaries for an interpretation. Jahrb. Römisch-Germanischen Zentralmus. Mainz, 1989, 36, 193–275.
  • Agrawal, D. P., Prehistoric copper technology in India : a review. In Metallurgy in India: A Retrospective (eds Rao, P. R. and Goswami, N. G.), National Metallurgical Laboratory, Jamshedpur, 2001, pp. 143–162.
  • Lahiri, N., Indian metal and metal-related artefacts as cultural signifiers: an ethnographic perspective. World Archaeol., 1995, 27, 116–132.
  • Lamberg-Karlovsky, C. C., Archeology and metallurgical technology in prehistoric Afghanistan, India and Pakistan. Am. Anthropol., 1967, 69, 145–162.
  • Balasubramaniam, R., Mungole, M. N., Prabhakar, V. N., Sharma, D. V. and Banerjee, D., Studies on Ancient Indian OCP period copper. Indian J. Hist. Sci., 2002, 37, 1–15.
  • Park, J. S. and Shinde, V., Iron technology of the ancient megalithic communities in the Vidarbha region of India. J. Archaeol. Sci., 2013, 40, 3822–3833.
  • Ray, A. and Chakrabarti, D. K., Studies in ancient Indian technology and production : a review. J. Econ. Soc. Hist. Orient., 1975, 18, 219–232.
  • Rai, S. S., Rai, N. K., Rai, A. K. and Chattopadhyaya, U. C., Rare earth elements analysis in archaeological pottery by laser induced breakdown spectroscopy. Spectrosc. Lett., 2016, 49, 57–62.

Abstract Views: 257

PDF Views: 122




  • Elemental Composition and Microstructure Analysis of Archaeological Copper from Central Ganga Valley, India

Abstract Views: 257  |  PDF Views: 122

Authors

Sidharth Shankar Rai
Department of History, Babasaheb Bhimrao Ambedkar University, Lucknow 226 025, India

Abstract


Copper alloys from an early-historic period site Kausambi, Uttar Pradesh, India were studied to understand the manufacturing technology and alloying practices through elemental analysis and microstructural examination. Most of the analysed samples were tin bronzes, and microstructure examination demonstrated casting, forging and annealing procedures adopted in manufacturing. Arsenic was absent in most of the samples, which may be due to recycling of the metal and awareness regarding the health hazards of this element among artisans. It is suggested that arsenic was not intentionally mixed in archaeological copper. On the other hand, tin was added in different quantities to meet the desired physical properties of the end-products. It is reported that copper metallurgy was developed in due course of time as a specialized craft in the Central Gangetic Valley, India and artisans of this region had mastered the copper-alloy technology since the early historic period.

Keywords


Archaeometallurgy, Copper Alloys, Early Historic Period, Elemental Composition, Microstructure Analysis.

References





DOI: https://doi.org/10.18520/cs%2Fv120%2Fi12%2F1894-1904