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Molecular Insights into Crystallization of Minerals: The Case of First-Row Transition Metal Salt Hydrates


Affiliations
1 Materials Chemistry Laboratory, Department of Chemistry, Indian Institute of Technology Delhi, New Delhi 110 016, India
 

How does Nature, the virtuoso chemist, assemble a mineral, an inorganic crystalline compound with a specific composition? How does one account for the directional interactions responsible for the final assembly of a crystal hydrate observed through an X-ray lens? Che­mical insights into the aggregation of molecules resulting into simple salt hydrates still evade experimental and theoretical studies. This article gives a perspective of how Nature dictates the structural landscape of MSO4–H2O in terms of supramolecular aggregation between the molecular species {M(H2O)6}2+, SO42- and H2O interacting at supersaturation through H-bonding and subsequent coordination forces.

Keywords

Crystallization, Hydrogen-Bonding, Salt Hydrates, Structural Landscape, Supramolecular Aggregation, Topotactic Reaction, Transition Metal.
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  • Molecular Insights into Crystallization of Minerals: The Case of First-Row Transition Metal Salt Hydrates

Abstract Views: 418  |  PDF Views: 141

Authors

Preethi Thomas
Materials Chemistry Laboratory, Department of Chemistry, Indian Institute of Technology Delhi, New Delhi 110 016, India
Shailabh Tewari
Materials Chemistry Laboratory, Department of Chemistry, Indian Institute of Technology Delhi, New Delhi 110 016, India
Manisha Jadon
Materials Chemistry Laboratory, Department of Chemistry, Indian Institute of Technology Delhi, New Delhi 110 016, India
Bharti Singh
Materials Chemistry Laboratory, Department of Chemistry, Indian Institute of Technology Delhi, New Delhi 110 016, India
Arunachalam Ramanan
Materials Chemistry Laboratory, Department of Chemistry, Indian Institute of Technology Delhi, New Delhi 110 016, India

Abstract


How does Nature, the virtuoso chemist, assemble a mineral, an inorganic crystalline compound with a specific composition? How does one account for the directional interactions responsible for the final assembly of a crystal hydrate observed through an X-ray lens? Che­mical insights into the aggregation of molecules resulting into simple salt hydrates still evade experimental and theoretical studies. This article gives a perspective of how Nature dictates the structural landscape of MSO4–H2O in terms of supramolecular aggregation between the molecular species {M(H2O)6}2+, SO42- and H2O interacting at supersaturation through H-bonding and subsequent coordination forces.

Keywords


Crystallization, Hydrogen-Bonding, Salt Hydrates, Structural Landscape, Supramolecular Aggregation, Topotactic Reaction, Transition Metal.

References





DOI: https://doi.org/10.18520/cs%2Fv122%2Fi1%2F39-46