Current Science

Open Access Open Access  Restricted Access Subscription Access

Lizardite–chrysotile veins from Vempalle Formation of Cuddapah Supergroup, India: a study in fluid–rock interaction


Affiliations
1 Geological Survey of India, Khanij Bhavan, Jaipur 302 004, India
2 Geological Survey of India, Seminary Hills, Nagpur 440 006, India
3 AD-18/5, Sector-I, Salt Lake City, Kolkata 700 064, India
4 Geological Survey of India, Dharitri Building, Sector V, Salt Lake City, Kolkata 700 091, India
 

Much work has been done on hydrothermal alteration and serpentinization of high-magnesian bulks like dunite or peridotite. In contrast, serpentinization of dolomite has received scant attention. In this study we focus on a system of nearly monomineralic intersecting veins comprising serpentine or epidote or calcite developed within Vempalle dolomite of unmetamorphosed Cuddapah Supergroup of rocks, Eastern Dharwar Craton, India. Our studies show that hydrothermal alteration under moderately low temperature, low pressure and moderate silica activity can lead to extensive serpentinization of the dolomitic host. Deve­lopment of talc can occur under increased silica activity at similar P–T conditions. We also explore the mecha­nism of formation of chrysotile veins, epidote veins and calcite veins that transect the lizardite which replaces dolomite

Keywords

Dolomite, fluid–rock interaction, lizardite and chrysotile veins, silica activity.
User
Notifications
Font Size

  • O’Hanley, D. S. and Wicks, J. F., Conditions of formation of lizardite, chrysotile, and antigorite, Cassiar, British Columbia. Can. Mineral., 1995, 33, 753–774.

  • O’Hanley D. S., Serpentinites: Records of Tectonic and Petrologic History, Oxford University Press, Oxford, UK, 1996, p. 277.

  • Evans, B. W., The serpentinite multisystem revisited: chrysotile is metastable. Int. Geol. Rev., 2004, 46, 479–506.

  • Normand, C., Williams-Jones, A. E., Martin, R. F. and Vali, H., Hydrothermal alteration of olivine in a flow-through autoclave: nucleation and growth of serpentine phases. Am. Mineral., 2002, 87, 1699–1709.

  • Berman, R. G., Engi, M., Greenwood, H. J. and Brown, T. H., Derivation of internally consistent thermodynamic data by the technique of mathematical programming; a review with application to the system MgO–SiO–H2O. J. Petrol., 1986, 27, 1331–1364.

  • Wicks, F. J. and Plant, A. G., Electron-microprobe and X-raymicrobeam studies of serpentine textures. Can. Mineral., 1979, 17, 785–830.

  • O’Hanley, D. S. and Dyar, M. D., The composition of lizardite 1T and the formation of magnetite in serpentinites. Am. Mineral., 1993, 78, 391–404.

  • Nagy, B. and Faust, G. T., Serpentines: natural mixtures of chrysotile and antigorite: Am. Mineral., 1956, 41, 817–838.

  • Dungan, M. A., Metastability in serpentine–olivine equilibria. Am. Mineral., 1977, 62, 1018–1029.

  • Evans, B. W., Metamorphism of alpine peridotite and serpentinite. Annu. Rev. Earth Planet. Sci., 1977, 5, 397–447.

  • Frost, B. R. and Beard, J. S., On silica activity and serpentinization. J. Petrol., 2007, 48, 1351–1368.

  • Evans, B. W., Control of the products of serpentinization by the Fe–Mg exchange potential of olivine and orthopyroxene. J. Petrol., 2008, 49, 1873–1887.

  • Evans, B. W., Lizardite versus antigorite serpentinite: magnetite, hydrogen and life(?). Geology, 2010, 38, 879–882.

  • Plumper, O., Piazolo, S. and Austrheim, H., Olivine pseudomorphs after serpentinized orthopyroxene record transient oceanic lithospheric mantle dehydration (Leka ophiolite complex, Norway). J. Petrol., 2012, 53, 1943–1968.

  • Majumdar, A. S., Hovelmann, J., Vollmer, C., Berndt, J., Mondal, S. K. and Putnis, A., Formation of Mg-rich olivine pseudomorphs in Serpentinized Dunite from the Mesoarchean Nuasahi Massif, eastern India: insights into the evolution of fluid composition at the mineral–fluid Interface. J. Petrol., 2015, 57(1), 3–26; doi: 10.1093/petrology/egv070.

  • King, W., The Kadapah and Karnul Formations in the Madras Presidency. Mem. Geol. Surv. India, 1872, 8(1), 1–346.

  • Lakshminarayan, G., Bhattacharjee, S. and Naidu, R., Sedimentation and tratigraphic framework in the Cuddapah Basin, AP. Geol. Surv. India Spec. Publ., 2001, 55(2), 31–57.

  • Chandrakala, K., Pandey, O. P., Mall, D. M. and Sarkar, D., Seismic signatures of a Proterozoic thermal plume below southwestern part of Cuddapah Basin, Dharwar Craton. J. Geol. Soc. India, 2010, 76, 565–572.

  • Chatterjee, N. and Bhattacharji, S., Petrology, geochemistry and tectonic settings of the mafic dikes and sills associated with the evolution of the Proterozoic Cuddapah Basin of south India. Proc. Indian Acad. Sci. (Earth Planet. Sci.), 2001, 110(4), 433–453.

  • Chakraborty, K., Mukhopadhyay, P. and Pankaj, P., Magmatism in western Cuddapahs: the mafic sills and lava flows of Vempalle and Tadpatri formations. J. Geol. Soc. India, 2016.

  • Srikantia, S. V., Kuppalapalle volcanic – a distinct upper Papaghni volcanic activity in the Cuddapah basin. J. Geol. Soc. India, 1984, 25(12), 775–779.

  • Downs, R., The RRUFF Project: an integrated study of the chemistry, crystallography, Raman and infrared spectroscopy of minerals. In Paper presented at the Program and Abstracts of the 19th General Meeting of the International Mineralogical Association, Kobe, Japan, 2006, O03–O13; http://rruff.info/

  • Groppo, C., Rinaudo, C., Cairo, S., Gastaldi, D. and Compagnoni, R., Micro-Raman spectroscopy for a quick and reliable identification of serpentine minerals from ultramafics. Eur. J. Mineral., 2006, 18, 319–329.

  • Holland, T. J. B. and Powell, R., An improved and extended internally consistent thermodynamic dataset for phases of petrological interest, involving a new equation of state for solids. J. Metamorph. Geol., 2011, 29(3), 309–343.

  • Connolly, J. A. D., Computation of phase equilibria by linear programming: a tool for geodynamic modeling and its application to subduction zone decarbonation. Earth Planet. Sci. Lett., 2005, 236, 524–541.

  • http://database.iem.ac.ru/mincryst

  • Speiler, A. R. and Bird, D. K., Epidote in geothermal systems. Rev. Mineral. Geochem., 2004, 56(1), 235–300; 10.2138/gsrmg.56.1.235.

  • Schroeder, T., Wolfgang, B., Niels, J., Svenja, J., Patrick, M. and Andreas, K., Fluid circulation and carbonate vein precipitation in the footwall of an oceanic core complex, Ocean Drilling Program Site 175, Mid-Atlantic Ridge. Geochem., Geophys., Geosyst., 2015, 16(1), 3716–3732; https://doi.org/10.1002/2015GC006041.

  • Young-Joon, Lee, Morse, J. W. and Wiltschko, D. V., An experimentally verified model for calcite precipitation in veins. Chem. Geol., 1996, 130(3–4); https://doi.org/10.1016/0009-2541(96)00008-3.

  • Chen, Y., Han, X., Wang, Y. and Lu, J., Precipitation of calcite veins in serpentinized harzburgite at Tianxiu hydrothermal field on Carlsberg Ridge (3.67°N), Northwest Indian Ocean: implications for fluid circulation. J. Earth Sci., 2020, 31(1), 91–101.

  • Saha, D., Chakraborty, S. and Tripathy, V., Intracontinental thrusts and inclined transpression along eastern margin of the East Dharwar Craton, India. J. Geol. Soc. India, 2010, 75, 323–337.

  • Tripathy, V. and Saha, D., Inversion of calcite twin data, paleostress reconstruction and multi-phase weak deformation in cratonic interior – evidence from the Proterozoic Cuddapah Basin, India. J. Struct. Geol., 2015, 77, 62–81.

  • Geology and Mineral Resources of India. Geological Survey of India, Miscellaneous Publication No. 30, 2010, part XXII.


Abstract Views: 349

PDF Views: 153




  • Lizardite–chrysotile veins from Vempalle Formation of Cuddapah Supergroup, India: a study in fluid–rock interaction

Abstract Views: 349  |  PDF Views: 153

Authors

Kasturi Chakraborty
Geological Survey of India, Khanij Bhavan, Jaipur 302 004, India
Praveer Pankaj
Geological Survey of India, Seminary Hills, Nagpur 440 006, India
Prabir Kumar Mukhopadhyay
AD-18/5, Sector-I, Salt Lake City, Kolkata 700 064, India
Sandip Nandy
Geological Survey of India, Dharitri Building, Sector V, Salt Lake City, Kolkata 700 091, India

Abstract


Much work has been done on hydrothermal alteration and serpentinization of high-magnesian bulks like dunite or peridotite. In contrast, serpentinization of dolomite has received scant attention. In this study we focus on a system of nearly monomineralic intersecting veins comprising serpentine or epidote or calcite developed within Vempalle dolomite of unmetamorphosed Cuddapah Supergroup of rocks, Eastern Dharwar Craton, India. Our studies show that hydrothermal alteration under moderately low temperature, low pressure and moderate silica activity can lead to extensive serpentinization of the dolomitic host. Deve­lopment of talc can occur under increased silica activity at similar P–T conditions. We also explore the mecha­nism of formation of chrysotile veins, epidote veins and calcite veins that transect the lizardite which replaces dolomite

Keywords


Dolomite, fluid–rock interaction, lizardite and chrysotile veins, silica activity.

References





DOI: https://doi.org/10.18520/cs%2Fv122%2Fi7%2F826-839