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Synthesis and Characterization of CDS Nanoparticles from Single Molecular Complex:Bis-(Thiourea)Cadmium(II)Acetate


Affiliations
1 Department of Physics, Midnapore College (Autonomous), Midnapore 721101, India
2 Department of Chemistry, Midnapore College (Autonomous), Midnapore 721101, India
     

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Metal Complex,bis-(thiourea)cadmium(II) acetate, have been successfully synthesized through reaction between thiourea with cadmium acetate in 1:2 ratio and characterized by spectroscopic analysis. The obtained complexhas been used as precursor andthermolyzedat 100°Cin ethylene glycol for the growth of crystalline CdS nanocompounds without using any external capping agents. The broadening of diffraction peaks in the X-ray diffractogramdepicted the nano-sized particles. Transmission electron microscopy (TEM) providesnon-spherical and irregular aggregates of particles size about 5.5 nm which were also confirmed by the measurement of crystallite size using Scherrer equation for the peaks of XRD. The emission spectra of nano-size CdS compounds showed the red shift (606 nm) than the bulk material.

Keywords

Cadmium Acetate, Metal Complex, Solvothermal, Nanocrystallites, Absorption and Emission Spectra.
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  • R. L Davidovich, V. Stavila and K. H Whitmire; Coordination Chemistry Reviews; 254 (2010)2193-2226

  • (a) D. Han, W. Yang, F. Gu and Z. Wang, Sensors and Actuators B: Chemical, 255 (2018) 1139-1146 (b) V. G. Charalampopoulos, B. M. Kariuki and K. D. M. Harris, Cryst. Growth Des., 2017, 17 (2), pp 786–793

  • M. Dominguez, E. Antico, ,A. Aguirre, S. G. Grandc and V. Salvado, Polyhedron, 21 (2002)1429-1437

  • A. E. Visser,R. P. Swatloski,W. M. Reichert,R. Mayton,SSheff,A. Wierzbicki,J. H. Davis, Jr. and R. D. Rogers, Environ. Sci. Technol. 36 (2002) 2523–2529

  • S. Parmar and Y. Kumar; ,Russian Journal of Inorganic Chemistry, 2010, 55, 361–367.

  • A. A. Isab andM. I. M. Wazeer, Journal of Coordination Chemistry, 2005, 58, 529-537.

  • L. Francois, M. Mostafavi, J. Belloni, J.A. Delaire, Phys. Chem. Chem. Phys. 3 (2001) 4965.

  • M. Nirmal, B.O. Dabbousi, M.G. Bawendi, J.J. Macklin, J.K.Trautman, T.D. Harris, L.E. Brus, Nature 383 (1996) 802.

  • Y.-C. Zhu, Y. Bo, Chem. Phys. Lett. 377 (2003) 367.

  • S. Wageh, L. Shu-Man, F.T. You, X. Xu-Rong, J. Lumin.102–103 (2003) 768.

  • V.I. Roldughin, Russ. Chem. Rev. 69 (2000) 821.

  • L. Guo, Q. Huang, X.-Y.Li, S. Yang, Phys. Chem. 3 (2001) 1661.

  • Z.-H. Yuan, L.-D. Zhang, J. Mater. Chem. 11 (2001) 1265.

  • Y.-W. Jun, C.-S. Choi, J. Cheon, Chem. Commun. (2001) 101.

  • M.A. Malik, P. O_Brien, N. Revaprasadu, J. Mater. Chem. 12 (2002) 92.

  • T. Trindade, P. O_Brien, X.-M. Zhang, M. Motevalli, J. Mater. Chem. 7 (1997) 1011.

  • P.S. Nair, T. Radhakrishnan, N. Revaprasadu, G.A. Kolawole, P. O_Brien, Polyhedron 22 (2003) 3129.

  • S.L. Cumberland, K.M. Hanif, A. Javier, G.A. Khitrov, G.F. Strouse, S.M. Woessner, C.S. Yun, Chem. Mater.14 (2002) 1576.

  • J. Zhang, B. Han, J. Liu, X. Zhang, Z. Liu, J. He, Chem. Commun.(2001) 2724.

  • J. Xu, Y. Li, J. Colloid Interface Sci. 259 (2002) 275.

  • Z.-L. Zhang, Q.-S.Wu, Y.-P.Ding, Inorg.Chem. Commun.6 (2003) 1393.

  • W.-H. Zhang, J.-l.Shi, H.-R.Shen, Z.-L.Hua, D.-S.Yan, Chem. Mater.13 (2000) 648.

  • F.J. Brieler, M. Froba, L. Chen, P.J. Klar, W. Heimbrodt, H.A.K.V. Nidda, Chem. Eur. J. 8 (2002) 187.

  • Y. Zhang, M. Ma, X. Wang, D. Fu, H. Zhang, N. Gu, J. Liu, Z. Lu, L. Xu, K. Chen, J. Phys. Chem. Solids 64 (2003) 927.

  • J.-X. Yao, G.-L.Zhao, G.-R. Han, Microelectron. Eng. 66 (2003) 115.

  • D. B. Wang, D. B. Yu, M. W. Shao, W. C. Yu and Y. T. Qian, Chem. Lett., 2002, 1056;

  • M. H. Chen and L. Gao, Mater. Res. Bull., 2005, 40, 1120;

  • Y. Yu, R. H. Wang, Q. Chen and L. M. Peng, J. Phys. Chem. B, 2006, 110, 13415;

  • J. Lu, Q. F. Han, X. J. Yang, L. D. Lu and X. Wang, Mater. Lett., 2008, 62, 2415;

  • H. W. Chang, B. Sarkar and C. W. Liu, Cryst. Growth Des., 2007, 7, 2691.

  • (a) J. Zhu, S. Liu, O. Palchik, Y. Koltypin, A. Gedanken, Journal of Solid State Chemistry153, 2000, 342-348 (b)J. Zhu,Y. Koltypin and A. Gedanken,Chem. Mater., 2000, 12 (1), 73–78 (c) J. Zhu,S. Liu, O. Palchik, Y. Koltypin and A. Gedanken,Langmuir, 2000, 16, 6396–6399

  • C. Zhao, X. B. Cao and X. M. Lan, Mater. Lett., 2007, 61, 5083;

  • B. Zhou and J. J. Zhu, Nanotechnology, 2009, 20, 085604.

  • K.Swaminathan and H.M.N.H.Irving; Journal of Inorganic and Nuclear Chemistry, 26, 1964, 1291-1294.

  • N. Maiti, S. H. Im, Y. H. Lee, C. H. Kim and S. I. Seok,Cryst. Eng. Comm, 2011, 13, 3767.

  • R. Rossetti, S. Nakahara, and L. E. Brus, The Journal of Chemical Physics 79, 1086 (1983)

  • O. Vigil and I. Riech, Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films 15, 2282 (1997)

  • B. Cullity, Elements of X-ray Diffraction, second ed., Addison-Wesley, Reading, MA, 1978.

  • R. Malik, J. Kaur, A. Kaushik, A. Sheoran, B. Chudasama, V. Kumar, K. B. Tikoo and S. Singhal, New J. Chem., 2017,41, 14088-14102

  • I. Jimenez, P.Salvador and F. Decker, Thin Solid Films 127, 1985, 305-312

  • V. Senthamilselvi, K. Ravichandran and K. Saravanakumar, Journal of Physics and Chemistry of Solids, 74, 2013, 65-69

  • P. A. Ajibade, D. C. Onwudiwe, M. J. Moloto, Polyhedron 30 (2011) 246–252

  • B. Gates, Y. Yin and Y. Xia, J. Am. Chem. Soc., 2000, 122, 12582.


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  • Synthesis and Characterization of CDS Nanoparticles from Single Molecular Complex:Bis-(Thiourea)Cadmium(II)Acetate

Abstract Views: 340  |  PDF Views: 7

Authors

M. N. Goswami
Department of Physics, Midnapore College (Autonomous), Midnapore 721101, India
Nilkamal Maiti
Department of Chemistry, Midnapore College (Autonomous), Midnapore 721101, India

Abstract


Metal Complex,bis-(thiourea)cadmium(II) acetate, have been successfully synthesized through reaction between thiourea with cadmium acetate in 1:2 ratio and characterized by spectroscopic analysis. The obtained complexhas been used as precursor andthermolyzedat 100°Cin ethylene glycol for the growth of crystalline CdS nanocompounds without using any external capping agents. The broadening of diffraction peaks in the X-ray diffractogramdepicted the nano-sized particles. Transmission electron microscopy (TEM) providesnon-spherical and irregular aggregates of particles size about 5.5 nm which were also confirmed by the measurement of crystallite size using Scherrer equation for the peaks of XRD. The emission spectra of nano-size CdS compounds showed the red shift (606 nm) than the bulk material.

Keywords


Cadmium Acetate, Metal Complex, Solvothermal, Nanocrystallites, Absorption and Emission Spectra.

References





DOI: https://doi.org/10.24906/isc%2F2018%2Fv32%2Fi5%2F180257