Journal of Surface Science and Technology

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Corrosion Inhibition of Mild Steel in 0.5N H2SO4 Solution by Tribulus terrestris (Fruit) Extract


Affiliations
1 Department of Chemistry, SPC Government College, Ajmer – 305004, Rajasthan, India
2 Department of Metallurgical and Materials, MNIT, Jaipur – 302017, Rajasthan, India
     

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The corrosion inhibition efficiency of alcoholic extract of fruits of plant Tribulus terrestris for mild steel in 0.5N H2SO4 solution has been studied in relation to concentration of inhibitor by Mass Loss, Potentiodynamic Polarisation and Electrochemical Impedance Spectroscopy methods. The results indicate that Tribulus terrestris fruit extract used in liquid H2SO4 effectively reduces the corrosion rate of mild steel and act as a good corrosion inhibitor. It is also observed that inhibition efficiency increases with inhibitor concentration but it decreases with increase in temperature. The thermodynamic parameters reveal that the inhibition of corrosion is due to adsorption of the inhibitor on the metal surface. The negative free energy values show spontaneity of the adsorption process in accordance with Langmuir adsorption isotherm.

Keywords

Corrosion Inhibitors, Electrochemical Method, Langmuir Adsorption Isotherm, Mass Loss Method, Tribulus terrestris.
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  • Corrosion Inhibition of Mild Steel in 0.5N H2SO4 Solution by Tribulus terrestris (Fruit) Extract

Abstract Views: 277  |  PDF Views: 4

Authors

Suchitra Chaudhary
Department of Chemistry, SPC Government College, Ajmer – 305004, Rajasthan, India
Rakesh K. Tak
Department of Chemistry, SPC Government College, Ajmer – 305004, Rajasthan, India
Rajendra Kumar Duchaniya
Department of Metallurgical and Materials, MNIT, Jaipur – 302017, Rajasthan, India

Abstract


The corrosion inhibition efficiency of alcoholic extract of fruits of plant Tribulus terrestris for mild steel in 0.5N H2SO4 solution has been studied in relation to concentration of inhibitor by Mass Loss, Potentiodynamic Polarisation and Electrochemical Impedance Spectroscopy methods. The results indicate that Tribulus terrestris fruit extract used in liquid H2SO4 effectively reduces the corrosion rate of mild steel and act as a good corrosion inhibitor. It is also observed that inhibition efficiency increases with inhibitor concentration but it decreases with increase in temperature. The thermodynamic parameters reveal that the inhibition of corrosion is due to adsorption of the inhibitor on the metal surface. The negative free energy values show spontaneity of the adsorption process in accordance with Langmuir adsorption isotherm.

Keywords


Corrosion Inhibitors, Electrochemical Method, Langmuir Adsorption Isotherm, Mass Loss Method, Tribulus terrestris.

References





DOI: https://doi.org/10.18311/jsst%2F2017%2F15575