Journal of Surface Science and Technology

Open Access Open Access  Restricted Access Subscription Access
Open Access Open Access Open Access  Restricted Access Restricted Access Subscription Access

Capparis decidua: A Green Inhibitor for Pure Aluminum Corrosion in Basic Media


Affiliations
1 Department of Chemistry, Faculty of Science, Yarmouk University, Irbid, Jordan
2 College of Pharmacy, Al Ain University of Science and Technology, Abu Dhabi, United Arab Emirates
     

   Subscribe/Renew Journal


Aluminum corrosion inhibition using Capparis decidua extract has been studied. The study was performed in a 1.0 M solution of sodium hydroxide and was monitored both by measuring mass-loss and by using electro-chemical and polarization methods. In addition, surface morphology analysis was performed by applying the technique of Scanning Electron Microscopy (SEM). Results demonstrate effectiveness of Capparis decidua extract as an inhibitor and the efficiency is both concentration and temperature dependent. Optimum (95.2%) inhibitor efficiency was found with maximum extract concentration at 45˚C. Results also show a slight decrease of aluminum dissolution upon increasing temperature using Capparis decidua extract. Based on Langmuir adsorption model, Capparis decidua adsorption on aluminum surface shows a high regression coefficient value. Based on the observed results, the activation enthalpy (ΔH#) and activation entropy (ΔS#) have been estimated and discussed. The value, and sign, of the thermodynamic adsorption free energy (ΔGoads) indicate that Capparis decidua extract undergoes physisorption on aluminum surface. A mixed-type inhibition of Capparis decidua extract has been concluded from electrochemical polarization studies. The study clearly shows that Capparis decidua extract acted against aluminum corrosion in alkaline media by forming a protective film on the top of aluminum surface which was determined by SEM results.

Keywords

Aluminium Corrosion, Corrosion, Green Inhibitor, Organic Inhibitor.
Subscription Login to verify subscription
User
Notifications
Font Size


  • D. Costa, T. Ribeiro, P. Cornette and P. Marcus, J. Phys. Chem. C., 120, 28607 (2016). https://doi.org/10.1021/acs.jpcc.6b00572, https://doi.org/10.1021/acs.jpcc.6b05783, https://doi.org/10.1021/acs.jpcc.6b09578.

  • G.T. Hefter, N.A. North and S.H. Tan, Corrosion, 53, 657 (1997) https://doi.org/10.5006/1.3290298.

  • T. Stimpfling, F. Leroux and H. Hintze‐Bruening, Europian Journal of Inorganic Chemistry, 32, 5396 (2012). https://doi.org/10.1002/ejic.201200504.

  • M. Metikos-Hukovic, R. Babic and Z. Guubac, Journal of Applied Electrochemistry, 28, 433 (1998). https://doi.org/10.1023/A:1003200808093.

  • S. Kaya, P. Banerjee, S. Kr. Saha, B. Tüzün and C. Kaya, RSC Advances, 6, 74550 (2016). https://doi.org/10.1039/ C6RA14548E

  • S. Şafak, B. Duran, A. Yurt and G. Türkoğlu, Corrosion Science, 54, 251 (2012). https://doi.org/10.1016/j.corsci.2011.09.026.

  • D. Njoku, I. O. Ikenna, E. Oguzie, K. Oguzie and N. Ibisi, Journal of Molecular Liquids, 219, 417 (2016). https://doi.org/10.1016/j.molliq.2016.03.049.

  • O. Abiola, N. Oforka, E. Ebenso and N. Nwinuka, AntiCorrosion Methods and Materials, 54, 219 (2007). https://doi.org/10.1108/00035590710762357.

  • G. Avwiri and F. OIgho, Materials Letters, 57, 3705 (2003) https://doi.org/10.1016/S0167-577X(03)00167-8.

  • M. Deyab, Journal of the Taiwan Institute of Chemical Engineers, 58, 536 (2016). https://doi.org/10.1016/j.jtice.2015.06.021.

  • R. Saleh and A. Shams Eldin, Corros. Sci., 12, 689 (1972). https://doi.org/10.1016/S0010-938X(72)91188-2.

  • O. Abiola and J. Otaigbe, Corros. Sci., 50, 242 (2008). https:// doi.org/10.1016/j.corsci.2007.06.013.

  • A. Yazdzad, T. Shahrabi and M. Hosseini, Mater. Chem. Phys., 109, 199 (2008). https://doi.org/10.1016/j.matchemphys.2007.11.012.

  • G. Gunsekaran and L. Chauhan, Electrochem. Acta. 49, 4387 (2004). https://doi.org/10.1016/j.electacta.2004.04.030.

  • M. Abu-Dalo, A. Othman, and N. Al-Rawashdeh, Int. J. Electrochem. Sci., 7 9303 (2012).

  • M. Doche, J. Rameau, R. Durand, and F. Novel-cattin, Corros. Sci., 41, 805 (2007). https://doi.org/10.1016/S0010938X(98)00107-3.

  • M. Al-Abdallah, A. Maayta, M. Al-Qudah and N. Al-Rawashdeh, The Open Corros. J., 2, 71 (2009). https:// doi.org/10.2174/1876503300902010071.

  • N. Subramanyam, B. Sheshadri and S. Mayanna, Corros. Sci., 34, 563 (1993). https://doi.org/10.1016/0010938X(93)90272-I.

  • P. Okafor, U. Ekpe, E. Ebenso, S. Umoren and K. Leizou Bull. Electrochem., 21, 347 (2005).

  • A. Maayta and N. Al-Rawashdeh, Corros. Sci., 46, 1129 (2004). https://doi.org/10.1016/j.corsci.2003.09.009.

  • N. Al-Rawashdeh and A. Maayta, Anti-Corros. Method. Mater., 52, 160 (2005). https://doi.org/10.1108/00035590510595157.

  • A. Ruosan and N. Al-Rawashdeh, Corros. Eng. Sci. Tech., 41, 235 (2006). https://doi.org/10.1179/174327806X132150.

  • A. Maayta and N. A. F. Al-Rawashdeh, J. Jordanian Chem., 5, 175 (2010).

  • R. Bothi, R. Abdul, O. Hasnah and A. Khalijah, Acta. Phys. Chim. Sin., 26, 2171 (2010). https://doi.org/10.3866/PKU.WHXB20100646.

  • E. Oguzi, Mater. Chem. Phys., 99, 441 (2006). https://doi.org/10.1016/j.matchemphys.2005.11.018.

  • E. Oguzi, Port Electrochim. Acta., 26, 303 (2008). https://doi.org/10.4152/pea.200803303.

  • M. El-Sayed, R. Erasmus and J. Comins, Corrosion Science., 50, 3439 (2008). https://doi.org/10.1016/j.corsci.2008.10.002.

  • E. Oguzie, G. Onuoha and A. Onuchukwu, Materials Chemistry and Physics, 89, 1305 (2005). https://doi.org/10.1016/j.matchemphys.2004.09.004.

  • A. Popova, E. Sokolova, S. Raicheva and M. Christov, Corrosion Science, 45, 33 (2003). https://doi.org/10.1016/ S0010-938X(02)00072-0.

  • L. Nnanna, B. Onwuagba, I. Mejeha and K. Okeoma, African Journal of Pure and Applied Chemistry, 4, 11 (2010).

  • E. Noor, International Journal of Electrochemical Science, 2, 996 (2007).

  • G. Mu, X. Li and G. Liu, Corrosion Science, 47, 1932 (2005). https://doi.org/10.1016/j.corsci.2004.09.020.

  • S. Abd El-Rehim, H. Hassan and M. Amin, Materials Chemistry and Physics, 70, 64 (2001). https://doi.org/10.1016/ S0254-0584(00)00468-5, https://doi.org/10.1016/S02540584(00)00462-4.

  • M. Gomma and M. Wahdan, Materials Chemistry and Physics, 39, 209 (1995). https://doi.org/10.1016/02540584(94)01436-K.

  • N. Subramanian and K. Ramakrishnaiah, Indian J Tech., 8, 369 (1970).

  • S. Umoren, I. Obot, E. Ebenso, P. Okafor, O. Ogbobe, and E. Oguzie, Anti-Corrosion Methods and Materials, 53, 277 (2006).

  • T. Bataineh, M. Al-Qudah, E. Nawafleh and N. Al-Rawashdeh, International Journal of Electrochemical Science, 9, 3543 (2014).

  • T. Ibrahim and M. Abou-Zour, International Journal of Electrochemical Science, 6, 6442 (2011).

  • A. Ali, H. Megahed, M Elsayed and A. El-Etre, Journal of Basic and Environmental Sciences, 1, 136 (2014).

  • T. Bataineh, M. Al-Qudah, E. Nawafleh and A. Ajlouni, Plumbago Europaea. Jordan Journal of Chemistry, 8, 169 (2013). https://doi.org/10.12816/0001526.


Abstract Views: 413

PDF Views: 1




  • Capparis decidua: A Green Inhibitor for Pure Aluminum Corrosion in Basic Media

Abstract Views: 413  |  PDF Views: 1

Authors

Mahmoud A. Al-Qudah
Department of Chemistry, Faculty of Science, Yarmouk University, Irbid, Jordan
Rasha S. Hamaideh
Department of Chemistry, Faculty of Science, Yarmouk University, Irbid, Jordan
Idrees F. Al-Momani
Department of Chemistry, Faculty of Science, Yarmouk University, Irbid, Jordan
Nezar Al-Bataineh
College of Pharmacy, Al Ain University of Science and Technology, Abu Dhabi, United Arab Emirates

Abstract


Aluminum corrosion inhibition using Capparis decidua extract has been studied. The study was performed in a 1.0 M solution of sodium hydroxide and was monitored both by measuring mass-loss and by using electro-chemical and polarization methods. In addition, surface morphology analysis was performed by applying the technique of Scanning Electron Microscopy (SEM). Results demonstrate effectiveness of Capparis decidua extract as an inhibitor and the efficiency is both concentration and temperature dependent. Optimum (95.2%) inhibitor efficiency was found with maximum extract concentration at 45˚C. Results also show a slight decrease of aluminum dissolution upon increasing temperature using Capparis decidua extract. Based on Langmuir adsorption model, Capparis decidua adsorption on aluminum surface shows a high regression coefficient value. Based on the observed results, the activation enthalpy (ΔH#) and activation entropy (ΔS#) have been estimated and discussed. The value, and sign, of the thermodynamic adsorption free energy (ΔGoads) indicate that Capparis decidua extract undergoes physisorption on aluminum surface. A mixed-type inhibition of Capparis decidua extract has been concluded from electrochemical polarization studies. The study clearly shows that Capparis decidua extract acted against aluminum corrosion in alkaline media by forming a protective film on the top of aluminum surface which was determined by SEM results.

Keywords


Aluminium Corrosion, Corrosion, Green Inhibitor, Organic Inhibitor.

References





DOI: https://doi.org/10.18311/jsst%2F2020%2F23534