Journal of Surface Science and Technology

Open Access Open Access  Restricted Access Subscription Access
Open Access Open Access Open Access  Restricted Access Restricted Access Subscription Access

Physicochemical Studies on Micelle Formation of Chromium-Aluminium Synthetic Tanning Materials in Various Environments with Reference to Application to Leather


Affiliations
1 Chamicel and FT NMR Laboratory, Central Leather Research Institute, Adyar, Madras-600 020, India
     

   Subscribe/Renew Journal


Conductometric and spectrophotometric results suggested that Cr-Al Synthetic tainning materials formed micelle, which, was determined in aqueous as well as in different additive environments at different temperatures: The association constants (KA) for binding of Syntan with glycine was determined and the thermodynamic parameters of the process evaluated. While urea demicellised the system, NaCl enhanced micellisation. Considering micelles as a new phase, the free energy of transfer of Syntan from aqueous to glycine, urea and NaCl were found out. It was observed that the concentration of Syntan above cmc (preferably 5 to 10 times of cmc) was useful for tanning process. The aim for the preparation of this particular Syntan was to study its fixation for initiating high shrinkage temperature and light fastness.
Subscription Login to verify subscription
User
Notifications
Font Size


Abstract Views: 217

PDF Views: 2




  • Physicochemical Studies on Micelle Formation of Chromium-Aluminium Synthetic Tanning Materials in Various Environments with Reference to Application to Leather

Abstract Views: 217  |  PDF Views: 2

Authors

A. B. Mandal
Chamicel and FT NMR Laboratory, Central Leather Research Institute, Adyar, Madras-600 020, India

Abstract


Conductometric and spectrophotometric results suggested that Cr-Al Synthetic tainning materials formed micelle, which, was determined in aqueous as well as in different additive environments at different temperatures: The association constants (KA) for binding of Syntan with glycine was determined and the thermodynamic parameters of the process evaluated. While urea demicellised the system, NaCl enhanced micellisation. Considering micelles as a new phase, the free energy of transfer of Syntan from aqueous to glycine, urea and NaCl were found out. It was observed that the concentration of Syntan above cmc (preferably 5 to 10 times of cmc) was useful for tanning process. The aim for the preparation of this particular Syntan was to study its fixation for initiating high shrinkage temperature and light fastness.