Journal of Surface Science and Technology

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Spectrophotometric Determination of Ferbam (Ferric Dimethyl-dithiocarbamate) by Dissolving its Copper (II) Complex into Triton X-100


Affiliations
1 Forschungszentrum GmbH, Institut fur Instrumentelle Analytik, Postfach 3640, 76021, Karlsruhe, Germany
2 Department of Chemistry, D. A. V. College, Jalandhar, Pubjab, India
3 Department of Chemistry, G. N. D. University, Amritsar, Punjab, India
4 Department of Chemistry, Punjabi University, Patiala, Punjab, India
     

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A new spectrophotometric method has been developed for the microdetermination of ferbam by the formation of its copper complex, i.e., copper dimethyldithiocarbamate, which is made water soluble by adding the nonionic surfactant, Triton X-100 (TX-100). The complex absorbs strongly at 430 nm. Beers's law is obeyed over the concentration range of 0.5-15.3 ppm. The optimum conditions have been developed. The method is simple, rapid, sensitive. It involves no extraction and can be safely employed for the determination of ferbam in commercial formulations, vegetables and grains.

Keywords

Ferbam, Copper, TX-100, Spectrophotometry, Analysis.
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  • Spectrophotometric Determination of Ferbam (Ferric Dimethyl-dithiocarbamate) by Dissolving its Copper (II) Complex into Triton X-100

Abstract Views: 256  |  PDF Views: 2

Authors

Ashok Kumar Malik
Forschungszentrum GmbH, Institut fur Instrumentelle Analytik, Postfach 3640, 76021, Karlsruhe, Germany
K. N. Kaul
Department of Chemistry, D. A. V. College, Jalandhar, Pubjab, India
B. S. Lark
Department of Chemistry, G. N. D. University, Amritsar, Punjab, India
A. J. L. Rao
Department of Chemistry, Punjabi University, Patiala, Punjab, India

Abstract


A new spectrophotometric method has been developed for the microdetermination of ferbam by the formation of its copper complex, i.e., copper dimethyldithiocarbamate, which is made water soluble by adding the nonionic surfactant, Triton X-100 (TX-100). The complex absorbs strongly at 430 nm. Beers's law is obeyed over the concentration range of 0.5-15.3 ppm. The optimum conditions have been developed. The method is simple, rapid, sensitive. It involves no extraction and can be safely employed for the determination of ferbam in commercial formulations, vegetables and grains.

Keywords


Ferbam, Copper, TX-100, Spectrophotometry, Analysis.