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Viscometric Investigations on Chromium Soaps in Benzene-Methanol Mixture


Affiliations
1 Department of Chemistry, Institute of Basic Science, (Agra University), Khandari, Agra 282002, India
     

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The density and viscosity of the solutions of chromium soaps (myristate, palmitate and stearate) in benzene-methanol (4:l V/V) mixture have been measured at a constant temperature 30 ± 0.05 °C). The density and viscosity results have been explained on the basis of equations proposed by Root, Einstein, Vand, Moulik and Jones-Dole. The values of molar volume obtained by using Einstein's and Vand's equations were found to be in close agreement. The results of Root's and Jones-Dole equation confirm that the soap-soap interactions are almost negligible in dilute solutions. The values of CMC for chromium soaps obtained from density and viscosity measurements were in agreement.

Keywords

Density, Viscosity, Chromium Soaps, Benzene-Methanol Mixture.
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  • Viscometric Investigations on Chromium Soaps in Benzene-Methanol Mixture

Abstract Views: 241  |  PDF Views: 2

Authors

K. N. Mehrotra
Department of Chemistry, Institute of Basic Science, (Agra University), Khandari, Agra 282002, India
Mamta Jain
Department of Chemistry, Institute of Basic Science, (Agra University), Khandari, Agra 282002, India

Abstract


The density and viscosity of the solutions of chromium soaps (myristate, palmitate and stearate) in benzene-methanol (4:l V/V) mixture have been measured at a constant temperature 30 ± 0.05 °C). The density and viscosity results have been explained on the basis of equations proposed by Root, Einstein, Vand, Moulik and Jones-Dole. The values of molar volume obtained by using Einstein's and Vand's equations were found to be in close agreement. The results of Root's and Jones-Dole equation confirm that the soap-soap interactions are almost negligible in dilute solutions. The values of CMC for chromium soaps obtained from density and viscosity measurements were in agreement.

Keywords


Density, Viscosity, Chromium Soaps, Benzene-Methanol Mixture.