Journal of Surface Science and Technology

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Biomimetic Oxidation of Flavanone with Hydrogen Peroxide Catalysed by 5, 10, 15, 20-tetra-(2', 6'-Dichloro Phenyl) Porphyrinatoiron(III) Chlorides in CTAB Reverse Micelles


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1 Department of Chemistry, University of Delhi, Delhi - 110007, India
     

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Oxidation of flavanone with hydrogen peroxide catalysed by 5, 10,15,20-tetra-(2', 6'-dichlorophenyl) porphyrinatoiron(III)chlorides gives trans-3-hydroxy-flavanones, and flavones in CTAB reverse micellar conditions. The yields of oxidation products are higher in CTAB reverse micellar conditions than in homogeneous and phase transfer conditions.

Keywords

Flavanone, 5, 10, 15, 20-Tetra-(2', 6'-Dichlorophenyl) Porphyrinatoiron(III) Chloride, CTAB Reverse Micelles, Oxidation.
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  • Biomimetic Oxidation of Flavanone with Hydrogen Peroxide Catalysed by 5, 10, 15, 20-tetra-(2', 6'-Dichloro Phenyl) Porphyrinatoiron(III) Chlorides in CTAB Reverse Micelles

Abstract Views: 223  |  PDF Views: 2

Authors

S. M. S. Chauhan
Department of Chemistry, University of Delhi, Delhi - 110007, India
Bhanu Kalra
Department of Chemistry, University of Delhi, Delhi - 110007, India
Anju Gulati
Department of Chemistry, University of Delhi, Delhi - 110007, India

Abstract


Oxidation of flavanone with hydrogen peroxide catalysed by 5, 10,15,20-tetra-(2', 6'-dichlorophenyl) porphyrinatoiron(III)chlorides gives trans-3-hydroxy-flavanones, and flavones in CTAB reverse micellar conditions. The yields of oxidation products are higher in CTAB reverse micellar conditions than in homogeneous and phase transfer conditions.

Keywords


Flavanone, 5, 10, 15, 20-Tetra-(2', 6'-Dichlorophenyl) Porphyrinatoiron(III) Chloride, CTAB Reverse Micelles, Oxidation.