Manufacturing Technology Today

Open Access Open Access  Restricted Access Subscription Access
Open Access Open Access Open Access  Restricted Access Restricted Access Subscription Access

Desorption of Crude Oil from Contaminated Sand using Surfactants


Affiliations
1 B.M.S College of Engineering, Department of Chemical Engineering, Bengaluru, India
     

   Subscribe/Renew Journal


Oil spill is a form of pollution that involves the release of oil into the environment. Oil forms an exterior coating on sand particles and due to its hydrophobicity, it is not washed away easily. It remains in soil matrix for a long time. This oil coating can be removed by different methods which include Shoreline flushing, solvent washing, booms, vacuum desorption, sorbents, biodegradable agents, microbial agents, bio-surfactants, incineration and mechanical removal. Desorption of the oil from the oil-sand-water mixture can be done using surfactants. Our basic aim is to remove crude from the contaminated sand which we came across different methods such as excavation, incineration, thermal desorption, composting, land farming and soil washing. We found that soil washing technique was easier compared to any other techniques based on their availability. The desorption of crude oil was done using anionic surfactant (SDS) and natural surfactant (Reetha). Based on this, different adsorption isotherms were applied and kinetics of desorption were studied.

Keywords

Oil Spill, Desorption Isotherm, Kinetics, Contaminated Sand, Surfactants.
User
Subscription Login to verify subscription
Notifications
Font Size

  • Khodaddi, A; Ganjidoust, Hossainp; Syed Razavi, SN: Treatment of crude oil contaminated soil using bio surfactants, 2012.

  • Bailey, GW; White, JL: Factors influencing the adsorption, desorption, and movement of pesticides in soil., Residue rev., 32, 1970, 29-92.

  • Rao, Bhakul H: Swaminathan, R; Asolekar, Shyam R: Washing of marine coastal sand in a batch Reactor, Sorption and Desorption of BTEX, 2016.

  • Boesten, J.J.T.I, Influence of soil/liquid ratio on the experimental error of sorption coefficients in relation to OECD guideline 106 proceedings of 5th international workshop on environmental behavior of pesticides and regulatory aspects, Brussels, 1994.

  • Brown DS; Flagg EW: Empirical prediction of organic pollutants sorption in natural sediments, 'Journal of Environmental Quality', vol. 10, no. 3, 1981, 382-386.

  • Black, CA; Evans DD; White JL; Ensminger LE; Clark FE., (eds): Methods of soil analysis”,vol 1 and 2, American society of Agronomy, Madison, WI, 1982.

  • Chiou, CT; Peters, LJ; Freed, VH: A physical concept of soil water equilibria for nonionic organic compounds, 'Science', vol. 206, 1979, 831-832.

  • Mulligan, CN; Yong, RN; Gibbs, BF: Surfactant Enhanced Remediation of Contaminated Soil, A Review, 2001, Engineering Geology, vol. 60, no. 1-4, 371-380.

  • Satterfield, CN; Ramachandran, PA; Chaudari, RV: 'Slurry Reactors', AICHe209, 87 (24), 1975, 1980, 74, 177.

  • Barnes, David L: Treatment of PetroleumContaminated Soil in Cold, Wet, Remote Egions, USDA Forest Service Technology and Development Program Missoula, MT, 2002.

  • Pop, Dorina; Micle, Valer: Influence of the Texture of the Efficiency of Thermal Desorption Process of Soils Contaminated With Crude Oil, vol. 3, no. 1, 2014, ISSN 20634803.

  • Knapik, Ewa; Stopa, Jerzy: Laboratory experiments for crude oil removal from water surface using nano silica as sorbent, Poland, vol. 31, no 2, 2014.

  • Bezza, Fisseha Andualem; Evans Martin Nkhalambayausi-Chirwa: Desorption Kinetics of Polycyclic Aromatic Hydrocarbons from Contaminated Soil and the Effect of bio surfactant supplementation on the rapidly desorbing Fractions, South Africa, vol. 29, no. 4, 2015, 680-688.

  • Giles, CH; McEwan, JH; Nakhwa, SN; Smith, D: Studies in Adsorption: XI. A system of classification of solution adsorption isotherms and its use in the diagnosis of adsorption mechanisms and in measurements of pesticides surface areas of soils, 'J.Chem.Soc', 1960, 3983-93.

  • Green, RE; Yamane, VK: Precision in pesticide adsorption measurements. 'Soil sci. Am. proc.', 34, 1970, 353-354.

  • Guth, JA: Adsorption/Desorption, in joint International Symposium, Physiochemical properties and their role in environmental hazard assessment, 1985, Canterbury, UK .

  • Hance, RJ: The speed of Attainment of Sorption Equilibria in Some Systems involving Herbicides, 'Weed research', vol. 7, no. 1, 1967, 29-36.

  • Fogler, HS and Brown, LF: (Reactors, ACS symposium series),1981, vol. 168, 31.

  • Haymaker, JW; Thompson, JM: Adsorption in organic chemicals in organic chemicals in the soil environment (goring C.A.I. and Hamaker J.W., eds), vol. 1 and 2, Marcel Dekker, New York, 1972, 49-143.

  • Yoon, Hyun Suk and Park, Jun Boum: Remediation Technique for Hydrocarbon Contaminated Soils by Surfactant Enchanced Desorption, Dept of Civil engg., Korea, 151-742.

  • ISO/DIS 10381 -5 Soil quality –sampling –part 5: Guidance on the investigation of the soil contamination of urban and industrial sites.

  • ISO 10381 -6, Soil quality- sampling – part 6: Guidance on the collection, handling and storage of soil for the assessment of aerobic microbial processes in the laboratory, 1993.

  • Buckley, JS: Wetting alteration of solid surface by crude oils and theirasphaltnss, Mexico, vol 53, 1998.

  • Seader, JD: Separation process principles, America, 2010, second edition.

  • Fu, Joseph Yuchun: A study of low salinity water flooding in 1D and 2D, the University of Texas at Austin, 2011.

  • Karickhoff; SW: Semi-empirical estimation of sorption of hydrophobic pollutants on natural sediments and soils, Chemosphere, vol. 10, no. 8, 1981, 833-846.

  • Pacwa-Plociniczak, Magdalena; Plaza, Grazyna A: Environmental Applications of Bio surfactants: Recent Advances, 2011, 134-78.

  • Gupta, K; Srivasthava, RK; Singh, AK: Bench Scale Treatability Studies of Contaminated Soil using Soil Washing Technique, Dept of civil engg, Uttar Pradesh, E-Journal of Chemistry, 7(I), 2010, 73- 80.

  • Chaprao, Marcos J; Ferreira, Isabela NS; Correa, Priscilla F; Rufino, Raquel D; Luna, Juliana M; Silva, Elais J; Sarubbo, Leoine A: Application of Bacterial and Biodegradable of Motor Oil from contaminated sand, 'Electronic journal of biotechnology', Brazil, 2015, 431-439.

  • Smit, Martijin PJ; Grotenhuisb, Tim; bruning, Harry; Rulkens, Wim H: Modelling Desorption Kinetics of a Persistant organic pollutant from field aged sediment using a Bi-disperse Particle size Distribution, 'J.soils Sediments', 2010, 10:119-126.

  • Thompson, Nwankwere Emeka; Casmir, Gimba; Emmanuel, Ndukwe Iioegbulam Goerge,Isuwa Kari admu,'International Journal of Scientific and Technology Research', ISSN 2277-8616, vol. 4, 2015.

  • Soos, M and Rajniak, P: Percolation Models of Adsorption – Desorption Kinetics with Hysteresis, Dept of Chemical and Biochemical Engg, Faculty of chemical and food technology, Slovak University of Technology, 56 (1), 2002, 62-69.

  • OECD Guideline for the Testing of Chemicals, Adsorption-desorption using a batch equilibrium method, 2000.

  • Abousnina, Rajab M; Manalo, Allan; lokuge, Weena; shiau, Jim: Oil contaminated sand: an emerging and suitable construction material, 2015, Australia.

  • Treybal, Robert E: Mass transfer operations, 3rd edition, McGraw-Hill Company, Singapore, 1980.

  • Maletic, Snezana; dalmacija, Bozo and Roncevic, Srdan: Petroleum hydrocarbon biodegradability in soil - implication for bioremediation, Republic of Serbia, 2013, Chapter 3.

  • Th. Abdel-Moghny, Ramadan, SA: Removing of Hydrocarbon Contaminated Soil via Air Flushing Enhanced by Surfactant, 2012.

  • Undabeytia, T; Nir, S; Rytwo, G; Morillo, E; Maqueda, V: Modelling Adsorption – Desorption Processes of Cd on Montmorillonite, no. 4, 1998, 423-428.

  • Ezeji, Uchechukwu E; Anyadoh, Sylvia O; Ibekwe, Vincent I: Clean up of Crude Oil – Contaminated Soil, Terrestrial and Aquatic Environmental Technology, 2007.

  • Akpoveta, Vincent O; Osakwe, Egharevba, Felix; Medjor, Weltime O; Asia, Imohimi O: Surfactant Enhanced Soil Washing Technique and its Kinetics on the Remediation of Crude Oil Contaminated Soil.

  • Chen, Xunjun: Modelling of Experimental Adsorption Isotherm data, ISSN 2078-2489, China, 2015, 6, 14- 22.


Abstract Views: 296

PDF Views: 0




  • Desorption of Crude Oil from Contaminated Sand using Surfactants

Abstract Views: 296  |  PDF Views: 0

Authors

N. C. Mookambika
B.M.S College of Engineering, Department of Chemical Engineering, Bengaluru, India
Sharath Kumar
B.M.S College of Engineering, Department of Chemical Engineering, Bengaluru, India
S. Nischal
B.M.S College of Engineering, Department of Chemical Engineering, Bengaluru, India
C. Soomrith
B.M.S College of Engineering, Department of Chemical Engineering, Bengaluru, India

Abstract


Oil spill is a form of pollution that involves the release of oil into the environment. Oil forms an exterior coating on sand particles and due to its hydrophobicity, it is not washed away easily. It remains in soil matrix for a long time. This oil coating can be removed by different methods which include Shoreline flushing, solvent washing, booms, vacuum desorption, sorbents, biodegradable agents, microbial agents, bio-surfactants, incineration and mechanical removal. Desorption of the oil from the oil-sand-water mixture can be done using surfactants. Our basic aim is to remove crude from the contaminated sand which we came across different methods such as excavation, incineration, thermal desorption, composting, land farming and soil washing. We found that soil washing technique was easier compared to any other techniques based on their availability. The desorption of crude oil was done using anionic surfactant (SDS) and natural surfactant (Reetha). Based on this, different adsorption isotherms were applied and kinetics of desorption were studied.

Keywords


Oil Spill, Desorption Isotherm, Kinetics, Contaminated Sand, Surfactants.

References