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Ultrasonic Study of Binary Solutions of Triethyl Amine With Alcohols


Affiliations
1 Department of Biochemistry, F.B.S. and H., R.A.U, Pusa, Samastipur-848125, India
2 Department of Physics, F.B.S. and H., R.A.U, Pusa, Samastipur-848125, India
 

Triethyl amineas well as methanol and ethanol are important aliphatic organic amino compound, which draw their importance as excellent solvents. The densities (ρ) and ultrasonic velocities (u) of binary mixtures of triethyl amine with methanol and ethanol have been determined experimentally at 298.15K, 303.15K and 308.15K respectively. Isentropic compressibility, intermolecular free length, molar volume, available volume and free volume have been computed utilizing these experimental data. The nonlinear variation of these parameters shows the presence of interaction and their excess values is indicative of interaction between the components molecules in both systems.

Keywords

Ultrasonic Velocity, Binary Mixtures of Triethylamine With Alcohols, Compressibility, Molecular Interaction.
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  • Ultrasonic Study of Binary Solutions of Triethyl Amine With Alcohols

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Authors

Narayani Prasad
Department of Biochemistry, F.B.S. and H., R.A.U, Pusa, Samastipur-848125, India
R. P. K. Ray
Department of Physics, F.B.S. and H., R.A.U, Pusa, Samastipur-848125, India
Manoj Kumar
Department of Physics, F.B.S. and H., R.A.U, Pusa, Samastipur-848125, India

Abstract


Triethyl amineas well as methanol and ethanol are important aliphatic organic amino compound, which draw their importance as excellent solvents. The densities (ρ) and ultrasonic velocities (u) of binary mixtures of triethyl amine with methanol and ethanol have been determined experimentally at 298.15K, 303.15K and 308.15K respectively. Isentropic compressibility, intermolecular free length, molar volume, available volume and free volume have been computed utilizing these experimental data. The nonlinear variation of these parameters shows the presence of interaction and their excess values is indicative of interaction between the components molecules in both systems.

Keywords


Ultrasonic Velocity, Binary Mixtures of Triethylamine With Alcohols, Compressibility, Molecular Interaction.