Journal of Pure and Applied Ultrasonics

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Ultrasonic Study and Allied Properties of the Binary Mixtures of Acetophenone and NN-Dimethylformamide With Benzyl Benzoate as Common Component


Affiliations
1 Department of Physics, S. V. U. P. G. Center, Kavali-524201, Andhra Pradesh, India
 

Ultrasonic velocity and density have been measured in the binary mixtures of acetophenone and NN-dimethylformamide with benzyl benzoate as common component at three temperatures 30, 40 and 50°C. Adiabatic compressibility, free length, molar volume etc. have been calculated and the excess parameters of these are employed for estimating the molecular interactions in the mixed state. Mostly strong and dipole-dipole interactions are indicated in the acetophenone and dimethylformamide systems at all concentrations. In both the systems endothermic type of reactions is suggested. From a theoretical evaluation of velocities, CFT, NOMOTO and JUNJIE appear to have an edge.

Keywords

Ultrasonic Velocity, Compressibility, Benzyl Benzoate, Molecular Interactions, Binary Mixtures.
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  • Ultrasonic Study and Allied Properties of the Binary Mixtures of Acetophenone and NN-Dimethylformamide With Benzyl Benzoate as Common Component

Abstract Views: 240  |  PDF Views: 0

Authors

N. Jaya Madhuri
Department of Physics, S. V. U. P. G. Center, Kavali-524201, Andhra Pradesh, India
J. Glory
Department of Physics, S. V. U. P. G. Center, Kavali-524201, Andhra Pradesh, India
P. S. Naidu
Department of Physics, S. V. U. P. G. Center, Kavali-524201, Andhra Pradesh, India
K. Ravindra Prasad
Department of Physics, S. V. U. P. G. Center, Kavali-524201, Andhra Pradesh, India

Abstract


Ultrasonic velocity and density have been measured in the binary mixtures of acetophenone and NN-dimethylformamide with benzyl benzoate as common component at three temperatures 30, 40 and 50°C. Adiabatic compressibility, free length, molar volume etc. have been calculated and the excess parameters of these are employed for estimating the molecular interactions in the mixed state. Mostly strong and dipole-dipole interactions are indicated in the acetophenone and dimethylformamide systems at all concentrations. In both the systems endothermic type of reactions is suggested. From a theoretical evaluation of velocities, CFT, NOMOTO and JUNJIE appear to have an edge.

Keywords


Ultrasonic Velocity, Compressibility, Benzyl Benzoate, Molecular Interactions, Binary Mixtures.