Journal of Pure and Applied Ultrasonics

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Excess Free Volume and Intermolecular Interactions in Binary and Ternary Liquid Mixtures


Affiliations
1 Department of Chemistry, Bundelkhand University, Jhansi, U.P., India
2 Department of Chemistry, Bipin Behari (P.G.) College, Jhansi, U.P., India
 

The free volume for the three binary liquid systems Bis (2-methoxy ethyl) ether+Nonane, Bis (2-methoxy ethyl) ether+Decane, Bis (2-methoxy ethyl) ether+Dodecane, and four ternary liquid systems Benzene+Chloroform+Cyclohexane, Toluene+Chloroform+Cyclohexane, Chlorobenzene+Chlorofoi in+Cyclohexane and Dioxane+Chloroform+Cyclohexane have been computed using viscosity and sound velocity data. Intermolecular interactions in these systems has been discussed in the light of excess free volume (VfE). The results are consistent with the theories.
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  • Excess Free Volume and Intermolecular Interactions in Binary and Ternary Liquid Mixtures

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Authors

Dhirendra Sharma
Department of Chemistry, Bundelkhand University, Jhansi, U.P., India
S. N. Srivastav
Department of Chemistry, Bipin Behari (P.G.) College, Jhansi, U.P., India

Abstract


The free volume for the three binary liquid systems Bis (2-methoxy ethyl) ether+Nonane, Bis (2-methoxy ethyl) ether+Decane, Bis (2-methoxy ethyl) ether+Dodecane, and four ternary liquid systems Benzene+Chloroform+Cyclohexane, Toluene+Chloroform+Cyclohexane, Chlorobenzene+Chlorofoi in+Cyclohexane and Dioxane+Chloroform+Cyclohexane have been computed using viscosity and sound velocity data. Intermolecular interactions in these systems has been discussed in the light of excess free volume (VfE). The results are consistent with the theories.