Journal of Pure and Applied Ultrasonics

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Estimation of Refractive Index, Viscosity, Ultrasonic Velocity and Surface Tension of Binary Mixtures of Ethyl Chloroacetate with Aromatic Liquids


Affiliations
1 Department of Physics, University of Lucknow, Lucknow-226007, India
2 Department of Chemistry, University of Allahabad, Allahabad-211002, India
 

Refractive indices, viscosity at 298 K, 303 K and 308 K and ultrasonic velocity at 298 K of five binary mixtures of ethyl chloroacetate (ECA) with benzene, toluene, 1,4-dimethyl benzene (p-xylene), 1,3,5-trimethyl benzene (mesitylene), and methoxybenzene (anisole) have been evaluated theoretically using various empirical relations applicable to binary mixtures. Relative merits and interrelation in these mixing rules have been discussed. An excellent agreement has been found between the experimental values with the respective values obtained from the mixing rules. Also, the extended statistical theory of Flory (FST) has been used to predict the surface tension of five binary systems at 298K. The values of surface tension thus obtained have been utilized to compute ultrasonic velocity using Auerbach relation. Theoretical values have been compared with the experimental values. The results have been discussed in terms of average percentage deviation (APD).
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  • Estimation of Refractive Index, Viscosity, Ultrasonic Velocity and Surface Tension of Binary Mixtures of Ethyl Chloroacetate with Aromatic Liquids

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Authors

Divya Shukla
Department of Physics, University of Lucknow, Lucknow-226007, India
Shahla Parveen
Department of Physics, University of Lucknow, Lucknow-226007, India
Manisha Gupta
Department of Physics, University of Lucknow, Lucknow-226007, India
J. P. Shukla
Department of Physics, University of Lucknow, Lucknow-226007, India
J. D. Pandey
Department of Chemistry, University of Allahabad, Allahabad-211002, India

Abstract


Refractive indices, viscosity at 298 K, 303 K and 308 K and ultrasonic velocity at 298 K of five binary mixtures of ethyl chloroacetate (ECA) with benzene, toluene, 1,4-dimethyl benzene (p-xylene), 1,3,5-trimethyl benzene (mesitylene), and methoxybenzene (anisole) have been evaluated theoretically using various empirical relations applicable to binary mixtures. Relative merits and interrelation in these mixing rules have been discussed. An excellent agreement has been found between the experimental values with the respective values obtained from the mixing rules. Also, the extended statistical theory of Flory (FST) has been used to predict the surface tension of five binary systems at 298K. The values of surface tension thus obtained have been utilized to compute ultrasonic velocity using Auerbach relation. Theoretical values have been compared with the experimental values. The results have been discussed in terms of average percentage deviation (APD).