Journal of Pure and Applied Ultrasonics

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Studies of Ultrasonic and Acoustic Parameters of Cu (II) Surfactant of Fresh and Treated Sesame and Soyabean Oils at High Temperature for Different Time


Affiliations
1 Department of Chemistry, Rajesh Pilot Government Polytechnic College, Dausa-303303, India
2 S.P.C. Government College, Ajmer-305001, India
3 Government P.G. College, Jhalawar-326001, India
 

Colloid chemical behavior and micellar characteristics of Cu (II) soaps derived from sesame and soyabean oils, (fresh oils and treated for 15 and 60 min.) at high temperature in benzene have been investigated and verified by ultrasonic velocity measurement. From these values, the specific acoustic impedance Z, adiabatic compressibility βad, intermolecular free length Lf, apparent molar compressibility Øk, molar sound velocity R, primary solvation number Sn have been calculated. The results have been analyzed in terms of Masson's equation. The results have been explained on the basis of solute-solvent interactions. The decrease in β and Lf with increasing concentration of the complex is indicating that there is sufficient solute- solvent interaction due to which micellar alignment is considerably affected.

Keywords

Copper Surfactants, Benzene, Sesame Oil, Soyabean Oil, Ultrasonic, Solute-Solvent Interaction.
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  • Saxena M., Sharma R. and Sharma A.K., Micellar Features of Cu (II) surfactants derived from edible oils "ISBN 978-620-2-01906-4" LAP Lambert Academic Publishing Germany (2017).

  • Sharma A.K., Saxena M. and Sharma R., Synthesis, spectroscopic and fungicidal studies of Cu (II) soaps derived from groundnut and sesame oils and their urea complexes, Bulletin of Pure and Applied Sciences, 36(2) (2017) 26-37.

  • Khan S., Sharma R. and Sharma A.K., Acoustic studies and other acoustic parameters of Cu(II) soap derived from nonedible neem oil (azadirecta indica), in non-aqueous media at 298.15, Acta Ac united Ac. 104 (2018) 277-283

  • Sharma A.K., Saxena M. and Sharma R., Synthesis, spectroscopic and biocidal activities of environmentally safe Agrochemicals, J. Biochem. Tech. 7(3) (2018) 1139-1147.

  • Tank P., Sharma R. and Sharma A.K., Studies of Ultrasonic and acoustic parameters of complexes derived from Copper (II) surfactant of mustard oil with N and S atoms containing ligands in non-aqueous media (benzene) at 303.15 K. J. Acous. Soc. Ind. 44(2) (2017) 87-99.

  • Bhutra R., Sharma R. and Sharma, A.K., Viscometric and CMC studies of Cu(II) surfactants derived from untreated and treated groundnut and mustard oils in non-aqueous solvent at 298.15 K, J. Inst. Chemists. 90 (2017) 29-47.

  • Sharma S., Sharma R. and Sharma A.K., Synthesis, Characterization, and thermal degradation of Cu (II) Surfactants for sustainable green chem, Asian J. Green Chem. 2(2) (2017) 129-140.

  • Sharma S., Sharma R., Heda L.C. and Sharma, A.K., Kinetic parameters and photo degradation studies of copper soap derived from soybean oil using ZnO as a Photo catalyst in solid and solution Phase, J. Inst. Chemists. 89(4) (2017) 119-136.

  • Tank P., Sharma R. and Sharma A.K., A pharmaceutical approach and antifungal activities of copper Soaps with their N and S donor complexes derived from mustard and soyabean oils, Glob. J. Pharmaceu. Sci. 3(4) (2017) GJPPS.MS.ID.555619.

  • Khan S., Sharma R. and Sharma A.K., Ultrasonic studies of Cu (II) Soap derived from seed oil of Pongamia pinnata (Karanj), in non-aqueous binary and ternary systems at 298.15K. Malaysian J. Chem. 19(2) (2017) 99-110.

  • Sharma A.K., Saxena M. and Sharma R., Ultrasonic studies of copper soaps urea complexes derived from mustard and soyabean oils. J. Phy. Sci. (2018) (Accepted).

  • Sharma A.K., Saxena M. and Sharma R., Ultrasonic studies of Cu (II) soaps derived from mustard and soybean oils. J. Pure Appl. Ultrason, 39(3) (2017) 92-99.

  • Tank P., Sharma R. and Sharma A.K., Micellar features and various interactions of copper soap complexes derived from edible mustard oil in benzene at 303.15 K. Curr. Phy. Chem. 8(1) (2018) 46-57.

  • Sharma R. and Sharma A.K., Natural edible oils: comparative health aspects of sesame, coconut, mustard (rape seed) and groundnut (peanut) a biomedical approach, Biomed. J. Sci. Tech. Res. 1(5) (2017) BJSTR.MS.ID.000441.

  • Tank P., Sharma A.K. and Sharma R., Thermal behaviour and kinetics of copper (II) soaps and complexes derived from mustard and soyabean oil, J. Anal. Pharm. Res. 4(2) (2017) 1-5.

  • Sharma A.K., Saxena M. and Sharma R., Ultrasonic studies of Cu (II) Soaps derived from Groundnut and Sesame oils, Tenside. Surf. Det. 55(2) (2018) 127-134.

  • Bhutra R., Sharma R. and Sharma A.K., Synthesis, Characterization and fungicidal activities of Cu (II) surfactants derived from groundnut and mustard oils treated at high temperatures, J. Inst. Chemists. 90(3) (2018) 66-80.

  • Sharma A.K., Sharma R. and Saxena M., Biomedical and antifungal application of Cu(II) soaps and its urea complexes derived from various oils, Open Access J. Trans. Med. Res. 2(2) (2018) 40-43.

  • Sharma A.K., Sharma S. and Sharma R., Thermal degradation of Cu (II) metallic soaps and their Characterizations. A pharmaceutical application, Chro. Phar Sci., 1(5) (2017) 312-319.

  • Sharma A.K., Saxena M. and Sharma R., Acoustic studies of copper Soap-urea complexes derived from groundnut and seasam oils. J. Phy. Studies, 21(4) (2017) 4601-6.


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  • Studies of Ultrasonic and Acoustic Parameters of Cu (II) Surfactant of Fresh and Treated Sesame and Soyabean Oils at High Temperature for Different Time

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Authors

Renu Bhutra
Department of Chemistry, Rajesh Pilot Government Polytechnic College, Dausa-303303, India
Rashmi Sharma
S.P.C. Government College, Ajmer-305001, India
Arun Kumar Sharma
Government P.G. College, Jhalawar-326001, India

Abstract


Colloid chemical behavior and micellar characteristics of Cu (II) soaps derived from sesame and soyabean oils, (fresh oils and treated for 15 and 60 min.) at high temperature in benzene have been investigated and verified by ultrasonic velocity measurement. From these values, the specific acoustic impedance Z, adiabatic compressibility βad, intermolecular free length Lf, apparent molar compressibility Øk, molar sound velocity R, primary solvation number Sn have been calculated. The results have been analyzed in terms of Masson's equation. The results have been explained on the basis of solute-solvent interactions. The decrease in β and Lf with increasing concentration of the complex is indicating that there is sufficient solute- solvent interaction due to which micellar alignment is considerably affected.

Keywords


Copper Surfactants, Benzene, Sesame Oil, Soyabean Oil, Ultrasonic, Solute-Solvent Interaction.

References