Journal of Pure and Applied Ultrasonics

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Effect of Tetra Alkyl Ammonium Chain Length and Dielectric Constant on Molecular Interaction Studies in Ternary Liquid Mixture of Dioxane, DMSO and H2O using Ultrasonic Technique


Affiliations
1 Department of Chemistry, University of Lucknow, Lucknow- 226007, India
 

Effect of lower to higher alkyl chain length cation (R4N+) of quaternary alkyl ammonium iodide salts and dielectric constant (ε) on thermo-physical properties in the homogeneous system of the ternary liquid mixtures of 1, 4-dioxane + dimethyl sulfoxide (DMSO) + water as well as the constituent binaries have been measured at 303.15 K, 313.15 K and 323.15K. The respective acoustical parameters were correlated as a function of the % composition using empirical and thermodynamic based relations. The data obtained from ultrasonic propagation parameters with variation in the % composition as well as dielectric constant (ε) of one of the component of the medium are provide a deep and meaningful picture of various interactions taking place in ternary and higher component liquid mixtures in terms of physical parameters. The reason for this study at different temperatures is that weak and strong complex formation that arises in hydrogen bonds. The present investigation has been under taken to study the nature of molecular interactions, molecular rearrangement and hydrogen making/breaking phenomena takes place.

Keywords

Ternary Liquid Mixture, Ion-Solvent Interactions, Dioxane-DMSO-H2O, Tetra Alkyl Ammonium Cation, Dielectric Constant.
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  • Caro M.N., Trenzado J.L., Galván S., Romano E., González E., Alcalde R. and Aparicio S., Densities and viscosities of three binary monoglyme + 1-alcohol system from (283.15 to 313.15K), J. Chem. Eng. Data, 58 (2013) 909-914.

  • Grande M.C., Julia J.A., Barrero C.R. and Marschoff C.M., Sound velocity measurement in water + acetonitrile system at temperature from 293.15 to 323.15K and its implications on the thermodynamic data processing, Phys. Chem. Liq., 51 (2013) 457-468.

  • Roy M.N., Sah R.S. and Pradhan P., Density, viscosity, sound speed, refractive indices and excess properties of binary mixtures of isoamyl alcohol with some alkoxy ethanol, I.J. Thermophys., 31 (2010) 316-326.

  • Attri P., Venkatesu P. and Hofman T., Temperature dependence measurements and structural characterization of trimethyl ammonium ionic liquid with a highly polar solvent, J. Phys. Chem. B, 115 (2011) 10086-10097.

  • Brigante M. and Sumbatyan M.A., Acoustic methods for the nondestructive testing of concrete: A review of foreign publications in the experimental field, Russ. J. Nondestr. Test, 49 (2013) 100-111.

  • Zade S.D., Study of molecular interactions of coumaran3-ones in polar and non polar solvent using ultrasonic interferometer, Rasayan J. Chem., 4 (2011) 620-629.

  • Kenart C.M. and Kenart W.J., Physico chemical methods used to study internal structures of liquid binary mixtures, Phys. Chem. Liq., 38 (2000) 155-180.

  • Senthil R.S. and Kubendran T.R., Viscosities and densities of binary mixtures of 1, 4-dioxane, carbon tetrachloride, and butanol at 303.15 K, 308.15 K, and 313.15 K, J. Chem. Eng. Data, 49 (2004) 421-425.

  • Frank H.S., Single ion activities and ion solvent interaction in dilute aqueous solution, J. Phys. Chem., 67 (1963) 1554.

  • Pathak R.N., Saxena I., Archna, Kumar R. and Singh N., Study of the influence of alkyl chain cation - solvent interactions on the slope ϕv vs √C curves in 1, 5-pentane diol-DMF solvent mixtures by apparent molar volume measurements, Trans. Faraday Soc., 3 (2014) 87-92.

  • Pathak R.N., Saxena I., Archna and Mishra A.K., Study of the influence of alkyl chain cation - solvent interactions on H2O structure in 1, 3-butanediol - H2O mixtures by apparent molar volume data, Ind. Council Chem., 26 (2009) 170.

  • Ali A. and Nabi F., Volumetric and Viscometric Studies of Molecular Interactions of Binary Liquid Mixtures of Styrene with Acetone and Dimethylsulphoxide at Different Temperatures, J. Dispersion Sci. Tech. 31 (2010) 1326-1334.

  • Conway B.E., Verrall R.E. and Desnoyers J.E., Partial molar volume of tetra alkyl ammonium halide and assignment of individual ionic contributions, Transac. Faraday Soc., 62 (1966) 2738-2749.

  • Pathak R.N. and Saxena I., Magnetic float densitometerA modified version, Ind. J. Eng. Mat. Sci., 5 (1998) 278-284.

  • Granados K. and Fredrique J.G., Refractive index, surface tension and density of aqueous mixture of carboxylic acids at 298.15 K, J. Chem. Eng. Data, 51 (2006) 1473-1478.


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  • Effect of Tetra Alkyl Ammonium Chain Length and Dielectric Constant on Molecular Interaction Studies in Ternary Liquid Mixture of Dioxane, DMSO and H2O using Ultrasonic Technique

Abstract Views: 296  |  PDF Views: 1

Authors

Indu Saxena
Department of Chemistry, University of Lucknow, Lucknow- 226007, India
Vijay Kumar
Department of Chemistry, University of Lucknow, Lucknow- 226007, India

Abstract


Effect of lower to higher alkyl chain length cation (R4N+) of quaternary alkyl ammonium iodide salts and dielectric constant (ε) on thermo-physical properties in the homogeneous system of the ternary liquid mixtures of 1, 4-dioxane + dimethyl sulfoxide (DMSO) + water as well as the constituent binaries have been measured at 303.15 K, 313.15 K and 323.15K. The respective acoustical parameters were correlated as a function of the % composition using empirical and thermodynamic based relations. The data obtained from ultrasonic propagation parameters with variation in the % composition as well as dielectric constant (ε) of one of the component of the medium are provide a deep and meaningful picture of various interactions taking place in ternary and higher component liquid mixtures in terms of physical parameters. The reason for this study at different temperatures is that weak and strong complex formation that arises in hydrogen bonds. The present investigation has been under taken to study the nature of molecular interactions, molecular rearrangement and hydrogen making/breaking phenomena takes place.

Keywords


Ternary Liquid Mixture, Ion-Solvent Interactions, Dioxane-DMSO-H2O, Tetra Alkyl Ammonium Cation, Dielectric Constant.

References