Indian Journal of Chemical Technology

Open Access Open Access  Restricted Access Subscription Access

NiO Nanoparticles Via Calcination of a Schiff Base Complex: Photocatalytic and Microbicidal Activity


Affiliations
1 Department of Chemistry, Faculty of Art and Science, University of Tokat Gaziosmanpaşa, 60240, Turkey
2 Department of Molecular Biology and Genetics, Faculty of Science, University of Bartın, 74100, Turkey
 

Calcination method has been used to create NiO nanoparticles with a diameter of 19 to 30 nm from [NiL] [L: 2,2'-((1E,1'E)-(1,2-phenylenebis(azanylylidene))bis(methanylylidene))bis(4-bromophenolate)]. Formation and purity of the NiO nanoparticles produced under mild conditions without any special needs are evidenced by fourier-transformed infrared (FT-IR) spectroscopy, ultraviolet visible (UV-Vis) spectroscopy, X-ray powder diffraction (XRD), energy-dispersive X-ray (EDX) spectroscopy and scanning transmission electron microscopy (STEM). According to the spectral methods, transformation of the synthesized nickel-Schiff base complex into the nanoparticles has been achieved with high purity, high crystallinity and low agglomeration by thermal decomposition which is an efficient and simple approach. The nanoparticles are employed as a catalyst for the decomposition of methylene blue, an industrial synthetic dye, and the nanoparticles exhibit mild photocatalytic activity. Furthermore, biological activity of nanoparticles has been investigated on five bacterial strains and two fungi, with promising results.

Keywords

Biological Activity, Calcination, Catalytic Activity, Industrial dyes, NiO nanoparticles
User
Notifications
Font Size

  • Saghatforoush L A, Mehdizadeh R & Chalabian F, Transit Met Chem, 35 (2010) 903.

  • Wu J, Xia X, Guo R, Huang X & Lin Y, Mater Res Bull, 96 (2017) 315.

  • Kheradmandfard M, Minouei H, Tsvetkov N, Vayghan A K & Kashani-Bozorg S F, Mater Chem Phys, 262 (2021) 1.

  • Wang H, Wei W & Hu Y H, Top Catal, 57 (2014) 607.

  • Weber S, Rath T, Mangalam J, Kunert B & Coclite A M, J Mater Sci Mater Electron, 29 (2018) 1847.

  • Nalage S R, Chougule M A, Sen S & Patil VB, J Mater Sci Mater Electron, 24 (2013) 368.

  • Mokoena T P, Hillie K T, Swart H C, Leshabane N & Tshilongo J, Mater Chem Phys, 253 (2020) 1.

  • Suvith V S, Devu V S & Philip D, Opt Quantum Electron, 52 (2020) 1.

  • Rammal M B & Omanovic S, Mater Chem Phys, 255 (2020) 123570.

  • Vijaya Kumar P, Jafar Ahamed A & Karthikeyan M, S N Appl Sci, 1 (2019) 1.

  • Jabli M, Al-Ghamdi Y O, Sebeia N, Almalki S G & Alturaiki W, Mater Chem Phys, 249 (2020) 1.

  • Ezhilarasi A A, Vijaya J J, Kennedy L J & Kaviyarasu K, Mater Chem Phys, 241 (2020) 1.

  • Mousa S A, El-Sayed E S R, Mohamed S S, Abo El-Seoud M A & Elmehlawy A A, Appl Microbiol Biotechnol, 105 (2021) 741.

  • Anandan K & Rajendran V, Mater Sci Semicond Process, 14 (2011) 43.

  • Brewster D A, Bian Y & Knowles K E, Chem Mater, 32 (2020) 2004.

  • Chai H, Chen X, Jia D, Bao S & Zhou W, Mater Res Bull, 47 (2012) 3947.

  • Wu H, Wang Y, Zheng C, Zhu J & Wu G, J Alloys Compd, 685 (2016) 8.

  • Patel K N, Deshpande M P, Gujarati V P, Pandya S & Sathe V, Mater Res Bull, 106 (2018) 187.

  • Du Y, Wang W, Li X, Zhao J & Ma J, Mater Lett, 68 (2012) 168.

  • Wang Y & Su Q, J Mater Sci Mater Electron, 27 (2016) 4752.

  • Grivani G, Vakili M, Khalaji A D, Bruno G & Rudbari H A, J Mol Struct, 1072 (2014) 77.

  • Selvakumar R, Nirosha B, Vairam S, Premkumar T & Govindarajan S, Inorganica Chim Acta, 482 (2018) 774.

  • Goel S, Tomar A K, Sharma R K & Singh G, ACS Appl Energy Mater, 1 (2018) 1540.

  • Karthik K, Dhanuskodi S, Gobinath C, Prabukumar S & Sivaramakrishnan S, J Mater Sci Mater Electron, 29 (2018) 5459.

  • Alagiri M, Ponnusamy S & Muthamizhchelvan C, J Mater Sci Mater Electron, 23 (2012) 728.

  • Zhu Z, Bai Y, Zhang T, Liu Z & Long X, Angew Chemie, 126 (2014) 12779.

  • Salehirad A, Russ J Appl Chem, 89 (2016) 63.

  • Salavati-Niasari M, Mir N & Davar F, J Alloys Compd, 493 (2010) 163.

  • Khansari A, Enhessari M & Salavati-Niasari M, J Clust Sci,

  • (2013) 289.

  • Khalaji A D & Das D, Int Nano Lett, 4 (2014) 1.

  • Grivani G, Ghavami A, Eigner V, Dušek M & Khalaji A D, Chinese Chem Lett, 26 (2015) 779.

  • Khalaji A D, Grivani G & Izadi S, J Therm Anal Calorim, 126 (2016) 1105.

  • Salehi M, Galini M, Kubicki M & Khaleghian A, Russ J Inorg Chem, 64 (2019) 18.

  • Dehno Khalaji A, J Clust Sci, 24 (2013) 189.

  • Farhadi S, Kazem M & Siadatnasab F, Polyhedron, 30 (2011) 606.

  • Farhadi S & Roostaei-Zaniyani Z, Polyhedron, 30 (2011) 971.

  • Farhadi S & Roostaei-Zaniyani Z, Polyhedron, 30 (2011) 1244.

  • Samadi S, Khalili E & Allahgholi Ghasri M R, J Electron Mater, 48 (2019) 7836.

  • Motahari F, Mozdianfard M R & Salavati-Niasari M, Process Saf Environ Prot, 93 (2015) 282.

  • Kitchamsetti N, Ramteke M S, Rondiya S R, Mulani S R & Patil M S, J Alloys Compd, 855 (2021) 157337.

  • Wang G, Li Y & Zhuo S, Int J Mater Res, 101 (2010) 310.

  • Ramesh M, Rao M P C, Anandan S & Nagaraja H, J Mater Res, 33 (2018) 601.

  • Miri A, Mahabbati F, Najafidoust A, Miri M J & Sarani M, Inorg Nano-Metal Chem, 52 (2022) 122.

  • Fasina T M, Ogundele O, Ejiah F N & Dueke-Eze C U, Int Juornal Biol Chem, (2012) 24. 45 Brandt A L, Castillo A, Harris K B, Keeton J T & Hardin M D, J Food Sci, 75 (2010) M557.

  • Parvekar P, Palaskar J, Metgud S, Maria R & Dutta S, Biomater Investig Dent, 7 (2020) 105.

  • Khalaji A D, Jafari K & Rad S M, Synth React Inorganic Met Nano-Metal Chem, 45 (2015) 875.

  • Motahari F, Mozdianfard M R, Soofivand F & Salavati- Niasari M, RSC Adv, 4 (2014) 27654.

  • Hussain M M, Rahman M M & Asiri A M, J Environ Sci (China), 53 (2017) 27.

  • Sheena P A, Priyanka K P, Sreedevi A & Varghese T, J Nanostructure Chem, 8 (2018) 207.

  • Siddique M N, Ahmed A, Ali T & Tripathi P, AIP Conf Proc, 1953 (2018).

  • Kalam A, Al-Sehemi A G, Al-Shihri A S, Du G & Ahmad T, Mater Charact, 68 (2012) 77.

  • Kawasaki S I, Sue K, Ookawara R, Wakashima Y & Suzuki A, J Supercrit Fluids, 54 (2010) 96.

  • Palanisamy P & Raichur A M, Mater Sci Eng C, 29 (2009) 199.

  • Zorkipli N N M, Kaus N H M & Mohamad A A, Procedia Chem, 19 (2016) 626.

  • Davar F, Fereshteh Z & Salavati-Niasari M, J Alloys Compd, 476 (2009) 797.

  • Chen Z, Xu A, Zhang Y & Gu N, Curr Appl Phys, 10 (2010) 967.

  • Khairnar S D & Shrivastava V S, J Taibah Univ Sci, 13 (2019) 1108.

  • Paul D & Neogi S, Mater Res Express, 6 (2019) 1. 60 Bhat S A, Zafar F, Mondal A H, Kareem A & Mirza A U, J Iran Chem Soc, 17 (2020) 215.

  • Al-Shawi S G, Alekhina N A, Aravindhan S, Thangavelu L & Kartamyshev N V, J Nanostructures, 11 (2021) 181.

  • Stoimenov P K, Klinger R L, Marchin G L & Klabunde K J, Langmuir, 18 (2002) 6679.

  • Chaudhary R G, Tanna J A, Gandhare N V, Rai A R & Juneja H D, Adv Mater Lett, 6 (2015) 990.

  • Khashan K S, Sulaiman G M, Ameer F A K A & Napolitano G, Pak J Pharm Sci, 29 (2016) 541.


Abstract Views: 111

PDF Views: 73




  • NiO Nanoparticles Via Calcination of a Schiff Base Complex: Photocatalytic and Microbicidal Activity

Abstract Views: 111  |  PDF Views: 73

Authors

Ayşegül Şenocak
Department of Chemistry, Faculty of Art and Science, University of Tokat Gaziosmanpaşa, 60240, Turkey
Rızvan İmamoğlu
Department of Molecular Biology and Genetics, Faculty of Science, University of Bartın, 74100, Turkey

Abstract


Calcination method has been used to create NiO nanoparticles with a diameter of 19 to 30 nm from [NiL] [L: 2,2'-((1E,1'E)-(1,2-phenylenebis(azanylylidene))bis(methanylylidene))bis(4-bromophenolate)]. Formation and purity of the NiO nanoparticles produced under mild conditions without any special needs are evidenced by fourier-transformed infrared (FT-IR) spectroscopy, ultraviolet visible (UV-Vis) spectroscopy, X-ray powder diffraction (XRD), energy-dispersive X-ray (EDX) spectroscopy and scanning transmission electron microscopy (STEM). According to the spectral methods, transformation of the synthesized nickel-Schiff base complex into the nanoparticles has been achieved with high purity, high crystallinity and low agglomeration by thermal decomposition which is an efficient and simple approach. The nanoparticles are employed as a catalyst for the decomposition of methylene blue, an industrial synthetic dye, and the nanoparticles exhibit mild photocatalytic activity. Furthermore, biological activity of nanoparticles has been investigated on five bacterial strains and two fungi, with promising results.

Keywords


Biological Activity, Calcination, Catalytic Activity, Industrial dyes, NiO nanoparticles

References