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A Historical Review of Electrode Materials and Electrolytes for Electrochemical Double Layer Supercapacitors and Pseudocapacitors


Affiliations
1 Conducting Polymers, Graphene Technology and Waste Management Group, Photovoltaic Metrology Section, Advance Materials and Devices Metrology Division, CSIR-National Physical Laboratory, Dr. K.S. Krishnan Marg, New Delhi 110 012, India
 

The supercapacitor is one of the most promising alternatives to other popular energy storage solutions, viz., rechargeable batteries and capacitors. They are considered the bridge between batteries (high energy density) and capacitors (high power density) because of their fast charge/discharge capacity, high specific power/energy, and good service-life, which make them the most promising candidate for future energy storage/redistribution systems as well as hybrid electric vehicles. In the past, much progress has occurred in electrode materials, electrode architecture, electrolytes, separators, and device configuration. This review article discusse the basics of electrochemical super capacitors, storage principal, device configuration, electrode materials, and electrolytes, including the coverage of the comprehensive literature account of the advancements in the area; and, finally, the discussion on technological challenges in the development of commercially viable next-gen supercapacitor devices.

Keywords

Supercapacitor, Ultracapacitor, Electrochemcial Double Layer Capacitor (EDLC), Pseudocapacitor, Activated Carbon, Carbon Nanotubes (CNTs), Carbon Aerogel, Graphene, Conducting Polymer, Polyaniline, Polypyrrole, Polythiophene, Hybrid Supercapacitors, Energy Density, Power Density, Ragone Plot.
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  • A Historical Review of Electrode Materials and Electrolytes for Electrochemical Double Layer Supercapacitors and Pseudocapacitors

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Authors

Parveen Saini
Conducting Polymers, Graphene Technology and Waste Management Group, Photovoltaic Metrology Section, Advance Materials and Devices Metrology Division, CSIR-National Physical Laboratory, Dr. K.S. Krishnan Marg, New Delhi 110 012, India

Abstract


The supercapacitor is one of the most promising alternatives to other popular energy storage solutions, viz., rechargeable batteries and capacitors. They are considered the bridge between batteries (high energy density) and capacitors (high power density) because of their fast charge/discharge capacity, high specific power/energy, and good service-life, which make them the most promising candidate for future energy storage/redistribution systems as well as hybrid electric vehicles. In the past, much progress has occurred in electrode materials, electrode architecture, electrolytes, separators, and device configuration. This review article discusse the basics of electrochemical super capacitors, storage principal, device configuration, electrode materials, and electrolytes, including the coverage of the comprehensive literature account of the advancements in the area; and, finally, the discussion on technological challenges in the development of commercially viable next-gen supercapacitor devices.

Keywords


Supercapacitor, Ultracapacitor, Electrochemcial Double Layer Capacitor (EDLC), Pseudocapacitor, Activated Carbon, Carbon Nanotubes (CNTs), Carbon Aerogel, Graphene, Conducting Polymer, Polyaniline, Polypyrrole, Polythiophene, Hybrid Supercapacitors, Energy Density, Power Density, Ragone Plot.

References