Research Journal of Pharmacy and Technology

Open Access Open Access  Restricted Access Subscription Access
Open Access Open Access Open Access  Restricted Access Restricted Access Subscription Access

Hydroquinone Solubility in Pure and Binary Solvent Mixture at Various Temperatures with FTIR


Affiliations
1 Department of Chemistry, M.S.G. College Malegaon Camp, Malegaon, Dist. Nashik, Pin 423105., India
     

   Subscribe/Renew Journal


Gravimetric method is used to measured hydroquinone solubility in water, ethanol and in water+ethanol binary mixtures at temperatures (293.15, 295.15, 298.15, 300.15, 303.15, 305.15, 308.15, 310.15 and 313.15)K. Mole fractions solubility of hydroquinone are correlated with temperature by using the Apelblat equation. The combined nearly ideal binary solvent (NIBS)-Redlich-Kister equation is used to fit experimental hydroquinone solubility data in mixed solvents at constant temperature. ΔH0soln, ΔG0soln, and ΔS0soln are thermodynamic functions of hydroquinone in different solvents, obtained from the modified van’t Hoff equation. FTIR study is done for some hydroquinone solution.

Keywords

Hydroquinone, Solubility, Density, Apelblat equation and FTIR.
Subscription Login to verify subscription
User
Notifications
Font Size


  • ODonoghue JL. Hydroquinone and its analogues in dermatology—a risk-benefit viewpoint. Journal of Cosmetic Dermatology. 2006; 5(3):196–203.

  • Enguita FJ. Leitão AL. Review Article: Hydroquinone: Environmental Pollution, Toxicity and Microbial Answers. Hindawi Publishing Corporation. BioMed International. 2013; Article ID 542168:14. doi.org/10.1155/2013/542168

  • Jurica K. et al. Arbutin and its metabolite hydroquinone as the main factors in the antimicrobial effect of strawberry tree (Arbutus unedo L.) leaves. Journal of Herbal Medicine. 2017; 172:S2210-8033(17)30020-9. doi.org/doi:10.1016/j.hermed.2017.03.006

  • Francisco J. Enguita. Leitão A L. Hindawi Publishing Corporation. BioMed Research International. 2013; Article ID 542168. doi.org/10.1155/2013/542168

  • Jagtap S. Magdum C. Influence of Water-soluble polymers on Epalrestat ternary complexation by kneading. Research. J. Pharm. and Tech 2019; 12(8):3602-3608.

  • Mishra R. Solubility Enhancement of Clarithromycin Using Solid Dispersion and Effervescence Assisted Fusion Technique Research J. Pharm. and Tech. 2016; 9(6):677-686.

  • Pawar RR, et al. Solubility, density and solution thermodynamics of NaI in different pure solvents and binary mixtures. J. Chem. Eng. Data. 2012; 5:3563-3572.

  • Pawar RR. et al. Solubility and density of potassium iodide in binary water-ethanol solvent mixtures at (298.15, 303.15, 308.15, and 313.15) K. J. Chem. Eng. Data. 2009; 54:935−37.

  • Pawar RR, et al. Solubility and density of potassium iodide in binary water-propan-1-ol solvent mixtures at (298.15,303.15,308.15 and 313.15) K. J. Chem. Eng. Data. 2010; 55: 1314−16.

  • Kadam UB. et al. Density, Viscosities and Ultrasonic Velocity Studies of Binary Mixtures of Chloroform with Propan-1-ol and Butan-1-ol at (303.15 and 313.150) K. J. Chem. Eng. Data. 2006; 51:60−63.

  • Hasan M. et al. Densities, Viscosities and Speed of Sound Studies of Binary Mixtures of Methylbenzene with Heptan-1-ol, Octan-1-ol and Decan-1-ol at (303.15 and 313.15) K. J. Chem. Eng. Data. 2006; 51:1922−26.

  • Marsh KN. Recommended Reference Materials for the Realisation of Physicochemical Properties. Blackwell Scientific Publications: Oxford. U.K. 1987.

  • Aher CS. Excess molar volume of aqueous 1-propanol and apparent molar volume of 2-naphthol in water, 1-propanol and their binary mixtures at various temperatures with DFT Study. J. Applicable Chem. 2018; 7(1):151-164.

  • Lourenço C. Melo C I. Bogel-Łukasik R. Bogel-Łukasik E. J. Chem. Eng. Data. 2012; 57:1525–1533.

  • Melo CI. Bogel-Łukasik R. Nunes da Ponte M. Bogel-Łukasik E. Fluid Phase Equilibria. 2013; 338:209–216.

  • Domańska U. Bogel-Łukasik R. J. Phys. Chem. B. 2005; 109:12124–12132.

  • Apelblat A. Manzurola E. J. Chem. Thermodyn. 1999; 31:85–91.

  • Gans P. et al. Investigation of equilibria in solution determination of equilibrium constants with hyperquad suite of program. Talanta. 1996; 43:1739–1753.

  • Guo H. et al. Measurement and correlation of solubility of pronamide in five organic solvents at (278.15-323.15)K. J. Chem. Thermodynamics. 2016; 99:11-15.

  • Jouyban A. et al. Solubility prediction of anthracene in mixed solvents using a minimum number of experimental data. Chem. Pharm. Bull. 2002; 50(1):25−25.

  • Joyce R. et al. Solubility of Anthracene in binary alcohol + 1,4-dioxane solvent mixtures. J. Chem. Eng. Data. 1995; 40:1124−1126.

  • Acree WE. Zvaigzne AI. Thermodynamic properties of nonelectrolyte solutions: part 4. estimation and mathematical representation of solute activity coefficients and solubilities in binary solvents using the NIBS and modified Wilson equations. Thermochim. Acta. 1991; 178:151−167.

  • Acree WE. Jr. Mathematical representation of thermodynamic properties: Part 2. Derivation of combined nearly ideal binary solvents NIBS/Redlich-Kister mathematical representation from a two body and three body interactional mixing model. Thermochim. Acta. 1992; 198:71−79.

  • Krug R. Hunter W G. Grieger R A. Enthalpy-Entropy Compensation. 2. Separation of the Chemical from the Statistical Effect. J. Phys. Chem. 1976; 80:2341−2351.

  • Cui Z. Yin Q. Gong J. WangY. Hao H. Xie C. Bao Y. Zhang M. Hau B. Wang. J. Fluid Phase Equilib. 2013; 337:354-362.

  • Mahajan MM. Raghuwanshi PB. Ultrasonic Velocity and Related Acoustical Parameters of N–(2-Hydroxybenzylidene)-3-Substituted Pyridine-2-Amine Schiff Bases in Ethanol-Water Mixture. J. Applicable Chem. 2016; 5(5):1208-1216.


Abstract Views: 94

PDF Views: 0




  • Hydroquinone Solubility in Pure and Binary Solvent Mixture at Various Temperatures with FTIR

Abstract Views: 94  |  PDF Views: 0

Authors

Chandrakant S. Aher
Department of Chemistry, M.S.G. College Malegaon Camp, Malegaon, Dist. Nashik, Pin 423105., India

Abstract


Gravimetric method is used to measured hydroquinone solubility in water, ethanol and in water+ethanol binary mixtures at temperatures (293.15, 295.15, 298.15, 300.15, 303.15, 305.15, 308.15, 310.15 and 313.15)K. Mole fractions solubility of hydroquinone are correlated with temperature by using the Apelblat equation. The combined nearly ideal binary solvent (NIBS)-Redlich-Kister equation is used to fit experimental hydroquinone solubility data in mixed solvents at constant temperature. ΔH0soln, ΔG0soln, and ΔS0soln are thermodynamic functions of hydroquinone in different solvents, obtained from the modified van’t Hoff equation. FTIR study is done for some hydroquinone solution.

Keywords


Hydroquinone, Solubility, Density, Apelblat equation and FTIR.

References