Research Journal of Pharmacy and Technology

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Electrochemical Behaviour of 4-aminoantipyrine at a Platinum Electrode: Kinetic Study


Affiliations
1 Department of Chemistry, Gurukula Kangri Vishwavidyalaya, Haridwar, Uttarakhand,, India
     

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In this work, electro-oxidation of 4-Aminoantipyrine is investigated by using cyclic voltammetry technique at platinum electrode. The oxidation process was shown to be irreversible over at the pH range 2.0 and the number of electron transferred in the process was calculated. Kinetic and electrochemical parameters for the reaction such as standard heterogeneous rate constant (k0, 2.145 x103 s-1), anodic electron transfer rate constant (kox, 2.316 x 103 s-1), electron dependence of the current on scan rate was examined for the electro-oxidation of 4-Aminoantipyrine. Electron transfer coefficient (α, 1.38) of reaction and formal potential (E0, 0.5562 V) of electrode were evaluated under the influence of scan rate.

Keywords

4-Aminoantipyrine, Cyclic Voltammetry, Kinetic Parameters, Electro-Oxidation, Water Pollution.
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  • Electrochemical Behaviour of 4-aminoantipyrine at a Platinum Electrode: Kinetic Study

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Authors

Dushyant Gangwar
Department of Chemistry, Gurukula Kangri Vishwavidyalaya, Haridwar, Uttarakhand,, India
Rajdeep Malik
Department of Chemistry, Gurukula Kangri Vishwavidyalaya, Haridwar, Uttarakhand,, India
Jasvinder Kaur
Department of Chemistry, Gurukula Kangri Vishwavidyalaya, Haridwar, Uttarakhand,, India

Abstract


In this work, electro-oxidation of 4-Aminoantipyrine is investigated by using cyclic voltammetry technique at platinum electrode. The oxidation process was shown to be irreversible over at the pH range 2.0 and the number of electron transferred in the process was calculated. Kinetic and electrochemical parameters for the reaction such as standard heterogeneous rate constant (k0, 2.145 x103 s-1), anodic electron transfer rate constant (kox, 2.316 x 103 s-1), electron dependence of the current on scan rate was examined for the electro-oxidation of 4-Aminoantipyrine. Electron transfer coefficient (α, 1.38) of reaction and formal potential (E0, 0.5562 V) of electrode were evaluated under the influence of scan rate.

Keywords


4-Aminoantipyrine, Cyclic Voltammetry, Kinetic Parameters, Electro-Oxidation, Water Pollution.

References