Open Access Open Access  Restricted Access Subscription Access

Heterogeneous Photocatalytic Treatment of Textile Effluent using Semiconductor Oxide under UV Irradiation


Affiliations
1 Department of Chemistry, Vellalar College for Women, Erode, Tamilnadu
 

The present work deals with the photocatalytic degradation as a method for pre-treatment of the effluent from a textile industry containing various dyes and their intermediates which are non-biodegradable. The textile effluent was subjected to photocatalytic degradation under UV irradiation in the presence of TiO2 as catalyst and the process parameters for maximum degradation were determined. Optimisation of catalyst dose and pH was carried out and the effect of addition of oxidant H2O2 on the degradation efficiency was also studied. The effectiveness with which the photocatalyst can be recycled was also assessed to ensure the economic viability of the process.

Keywords

Heterogeneous Photocatalysis, Semiconductor Oxide, Textile Effluent, Titanium Dioxide.
User
Notifications
Font Size


  • Prevot A.B., Baiocchi C., Brussino M.C., Pramauro E., Savarino P., Augugliaro V., “Photocatalytic degradation of acid blue 80 in aqueous solutions containing TiO2 suspension”, Environ. Sci. Technol, vol. 35, p. 971–976, 2001.
  • Vinodgopal K., Kamat P.V.,“Photochemistry of textile azo dyes. Spectral characterization of excited state reduced and oxidized forms of acid orange 7”, Photochem Photobiol A: Chem., vol. 83, p. 141–146, 1994.
  • Hachem C., Bocquillon F., Zaharaa O., Bouchy M., “Decolorization of textile industry wastewater by the photocatalytic degradation process”, Dyes Pigments, vol. 49, p. 117–125, 2001.
  • Konstantinou I.K., Albanis T.A., “TiO2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations: A review”, Appl.Catal. B: Environ., vol. 49, p. 1–14.
  • Poulios I., Aetopoulou I., “Photocatalytic Degradation of the Textile Dye Reactive Orange 16 in the Presence of TiO2 Suspensions”, Environ. Technol., vol. 20, p. 479–488,1999.
  • Epling G.A., Lin C., “Photoassisted bleaching of dyes utilizing TiO2 and visible light”, Chemosphere, vol. 46, pp. 561–570, 2002.
  • Tang W.Z., Zhang Z., An H., Quintana M.O., Torres D.F., “TiO2/UV Photodegradation of Azo Dyes in Aqueous Solutions”, Environ Technol., vol. 18, p. 1–12,1997.
  • KavithaS. K., Palanisamy P.N., “Photocatalytic degradation of Vat yellow 4 under UV/TiO2”, Modern Applied Sci., vol.4, p. 90–142, 2010.
  • Neppolian B., Choi H.C., Sakthivel S., Arabindoo B., Murugesan V., “Solar light induced and TiO2 assisted degradation of textile dye Reactive Blue 4”, Chemosphere, vol. 46, p. 1173–1181, 2002.
  • Arslan I., Balcioglu I.A., Tuhkanen T., Bahnemann D. “H2O2 /UV-C and Fe2+/H2O2/UV-C versus TiO2/UV-A treatment for reactive dye wastewater”, J. Environ. Engg., vol. 126, p. 903–911, 2000.
  • Bahnemann D.W., Cunningham J., Fox M.A., Pelizzetti E., Pichat P., Serpone N., Helz G.R., Zepp R.G., Crosby D.G., Acquatic and Surface Photochemistry, CRC Press, Boca Raton, Florida, p. 261–316, 1994.
  • Chun H., Yizhong W., “Decolorization and biodegradability of photocatalytic treated azo dyes and wool textile wastewater”, Chemosphere, vol. 39(12), p. 2107–2115, 1999.

Abstract Views: 724

PDF Views: 384




  • Heterogeneous Photocatalytic Treatment of Textile Effluent using Semiconductor Oxide under UV Irradiation

Abstract Views: 724  |  PDF Views: 384

Authors

S. K. Kavitha
Department of Chemistry, Vellalar College for Women, Erode, Tamilnadu

Abstract


The present work deals with the photocatalytic degradation as a method for pre-treatment of the effluent from a textile industry containing various dyes and their intermediates which are non-biodegradable. The textile effluent was subjected to photocatalytic degradation under UV irradiation in the presence of TiO2 as catalyst and the process parameters for maximum degradation were determined. Optimisation of catalyst dose and pH was carried out and the effect of addition of oxidant H2O2 on the degradation efficiency was also studied. The effectiveness with which the photocatalyst can be recycled was also assessed to ensure the economic viability of the process.

Keywords


Heterogeneous Photocatalysis, Semiconductor Oxide, Textile Effluent, Titanium Dioxide.

References





DOI: https://doi.org/10.15613/sijrs%2F2015%2Fv2i2%2F114281