Journal of Environment and Sociobiology

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Synthesis, Characterization, Structure and Antibacterial Activity of Fe (III) Complex with Tetradentate Phenol-Based N2O2 Ligand


Affiliations
1 Department of Chemistry, Sidho-Kanho-Birsha University, Purulia-723104, West Bengal, India
2 Department of Botany, Raghunathpur College, Raghunathpur, Purulia-723133, West Bengal, India
3 Department of Organic Chemistry, Indian Association for the Cultivation of Science, Kolkata-700032, India
4 Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Kolkata-700032, India
     

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Fe (III) complex with sterically constrained phenol based tetradentate N2O2 ligand together with acetylacetone as ancillary ligand has been synthesized and characterized. Sterically constrained tetradentate ligand N,N'-dimethyl-N,N'-bis(2-hydroxy-3,5-dimethylbenzyl)-ethylenediamine (H2L) has been used here to synthesize mono nuclear octahedral mixed ligand Fe(III) complex 1. Characterization of this compound is carried out by electronic spectroscopy, ESI - MS and single crystal X-ray crystallography. Compound 1 crystalizes in monoclinic space group P 21/n with a = 8.43 Å, b = 15.136 Å, c = 21.105 Å and z = 4. Antibacterial activity of complex 1 was performed by well plate technique. In the above experiment both Bacillus cereus and Escherichia coli were sensitive to the mononuclear mixed ligand complex [FeIIIL(acac)] 1.

Keywords

Syntheses, Characterization, X-Ray Structure, Electronic Spectra, Antibacterial Activity.
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  • Synthesis, Characterization, Structure and Antibacterial Activity of Fe (III) Complex with Tetradentate Phenol-Based N2O2 Ligand

Abstract Views: 374  |  PDF Views: 1

Authors

Debdas Mandal
Department of Chemistry, Sidho-Kanho-Birsha University, Purulia-723104, West Bengal, India
Subrata Raha
Department of Botany, Raghunathpur College, Raghunathpur, Purulia-723133, West Bengal, India
Trilochan Rakshit
Department of Chemistry, Sidho-Kanho-Birsha University, Purulia-723104, West Bengal, India
Ayan De Das
Department of Chemistry, Sidho-Kanho-Birsha University, Purulia-723104, West Bengal, India
Keshab Ch. Ghosh
Department of Organic Chemistry, Indian Association for the Cultivation of Science, Kolkata-700032, India
Partha Mitra
Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Kolkata-700032, India

Abstract


Fe (III) complex with sterically constrained phenol based tetradentate N2O2 ligand together with acetylacetone as ancillary ligand has been synthesized and characterized. Sterically constrained tetradentate ligand N,N'-dimethyl-N,N'-bis(2-hydroxy-3,5-dimethylbenzyl)-ethylenediamine (H2L) has been used here to synthesize mono nuclear octahedral mixed ligand Fe(III) complex 1. Characterization of this compound is carried out by electronic spectroscopy, ESI - MS and single crystal X-ray crystallography. Compound 1 crystalizes in monoclinic space group P 21/n with a = 8.43 Å, b = 15.136 Å, c = 21.105 Å and z = 4. Antibacterial activity of complex 1 was performed by well plate technique. In the above experiment both Bacillus cereus and Escherichia coli were sensitive to the mononuclear mixed ligand complex [FeIIIL(acac)] 1.

Keywords


Syntheses, Characterization, X-Ray Structure, Electronic Spectra, Antibacterial Activity.

References