Journal of Environment and Sociobiology

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Synthesis, Characterization, Structure and Antibacterial Activity of Fe (III) Complex with Tetradentate Phenol-Based N2O2 Ligand


Affiliations
1 Department of Chemistry, Sidho-Kanho-Birsha University, Purulia-723104, West Bengal, India
2 Department of Botany, Raghunathpur College, Raghunathpur, Purulia-723133, West Bengal, India
3 Department of Organic Chemistry, Indian Association for the Cultivation of Science, Kolkata-700032, India
4 Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Kolkata-700032, India
     

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Fe (III) complex with sterically constrained phenol based tetradentate N2O2 ligand together with acetylacetone as ancillary ligand has been synthesized and characterized. Sterically constrained tetradentate ligand N,N'-dimethyl-N,N'-bis(2-hydroxy-3,5-dimethylbenzyl)-ethylenediamine (H2L) has been used here to synthesize mono nuclear octahedral mixed ligand Fe(III) complex 1. Characterization of this compound is carried out by electronic spectroscopy, ESI - MS and single crystal X-ray crystallography. Compound 1 crystalizes in monoclinic space group P 21/n with a = 8.43 Å, b = 15.136 Å, c = 21.105 Å and z = 4. Antibacterial activity of complex 1 was performed by well plate technique. In the above experiment both Bacillus cereus and Escherichia coli were sensitive to the mononuclear mixed ligand complex [FeIIIL(acac)] 1.

Keywords

Syntheses, Characterization, X-Ray Structure, Electronic Spectra, Antibacterial Activity.
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  • Abu-Dief, A. M. and Mohamed, I. M. A. 2015. A review on versatile applications of transition metal complexes incorporating Schiff bases. Beni - suf University Journal of Basic and Applid Sciences, 4: 119-133.

  • Lakhe, D. and Mangaonkar, K. V. 2013. Synthesis, characterization and antimicrobial activity of mixed Ligand complexes of Ni(II), Cu(II) and Fe(III) ions with [phenol-2-[(3-methylphenyl) imino]methyl-4-nitro3-] and [phenol-2-[(3-chlorophenyl)imino]methyl-4-nitro-]. International Journal of Chem. Tech. Research, 5(1): 293-298.

  • Lever, A. B. P. 1984. Inorganic Electronic Spectroscopy, 2nd ed., Elsevier Science, The Netherlands.

  • Mandal, D., Abtab, S. M. T., Audhya, A., Tiekink, E. R. T., Endo, A., Clerac, R. and Chaudhury, M. 2013. Targeted syntheses of homo- and hetero-trinuclear complexes involving MII-NiII-MII (M = Ni, Cu, and Pd) nonlinear core: Structure, spectroscopy, magnetic and redox studies. Polyhedron, 52: 355-363.

  • Mandal, D., Chatterjee, P. B., Ganguly, R., Tiekink, E. R. T., Clerac, R. and Chaudhury, M. 2008. Tetra and dinuclear Nickel(II)-Vanadium(IV/V) heterometal complexes of a Phenol- based N2O2 ligand: Synthesis, structures, and magnetic and Redox properties. Inorg. Chem., 47: 584-591.

  • Nagajothi, A., Kiruthika, A., Chitra, S. and Parameswari, K. 2013. Fe(III) complexes with Schiff base Ligands: Synthesis, characterization and antimicrobial studies. Research Journal of Chemical Sciences, 3(2): 35-43.

  • Nakamoto, K. 1978. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd ed.; Wiley-Interscience: New York.

  • Perrin, D. D., Armarego, W. L. F. and Perrin, D. R. 1980. Purification of Laboratory Chemicals. Peragamon, Oxford.

  • Sheldrick, G. M. 1990. SHELXS 97, Acta Cryst. A46: 467.

  • Whittaker, J. W. 1994 Metal Ions in Biological Systems; Sigel, H., Sigel, A., (Eds.); Marcel Decker: New York.

  • Wu, A. M., Hahn, J. E. P. and Pecoraro, V. L. 2004. Chem. Rev., 104: 903-938.


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  • Synthesis, Characterization, Structure and Antibacterial Activity of Fe (III) Complex with Tetradentate Phenol-Based N2O2 Ligand

Abstract Views: 376  |  PDF Views: 1

Authors

Debdas Mandal
Department of Chemistry, Sidho-Kanho-Birsha University, Purulia-723104, West Bengal, India
Subrata Raha
Department of Botany, Raghunathpur College, Raghunathpur, Purulia-723133, West Bengal, India
Trilochan Rakshit
Department of Chemistry, Sidho-Kanho-Birsha University, Purulia-723104, West Bengal, India
Ayan De Das
Department of Chemistry, Sidho-Kanho-Birsha University, Purulia-723104, West Bengal, India
Keshab Ch. Ghosh
Department of Organic Chemistry, Indian Association for the Cultivation of Science, Kolkata-700032, India
Partha Mitra
Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Kolkata-700032, India

Abstract


Fe (III) complex with sterically constrained phenol based tetradentate N2O2 ligand together with acetylacetone as ancillary ligand has been synthesized and characterized. Sterically constrained tetradentate ligand N,N'-dimethyl-N,N'-bis(2-hydroxy-3,5-dimethylbenzyl)-ethylenediamine (H2L) has been used here to synthesize mono nuclear octahedral mixed ligand Fe(III) complex 1. Characterization of this compound is carried out by electronic spectroscopy, ESI - MS and single crystal X-ray crystallography. Compound 1 crystalizes in monoclinic space group P 21/n with a = 8.43 Å, b = 15.136 Å, c = 21.105 Å and z = 4. Antibacterial activity of complex 1 was performed by well plate technique. In the above experiment both Bacillus cereus and Escherichia coli were sensitive to the mononuclear mixed ligand complex [FeIIIL(acac)] 1.

Keywords


Syntheses, Characterization, X-Ray Structure, Electronic Spectra, Antibacterial Activity.

References