Open Access
Subscription Access
Open Access
Subscription Access
One Hundred Years of Ghosh’s Strong Electrolyte Theory
Subscribe/Renew Journal
Abnormal behaviour of strong electrolytes was a hot research topic around the turn of twentieth century. In 1918, J. C. Ghosh published a series of articles dealing with this abnormal behaviour and suggested a cube ischolar_main law for data correlation. The publications were both praised and criticised. Debye and Huckel published in 1923 their well-known theory of strong electrolytes, the square ischolar_main law, which completely overshadowed Ghosh’s theory. By the middle of twentieth century, however, Ghosh’s theory became prominent again, particularly for concentrated electrolyte solutions, in the light of pseudo-lattice theory of strong electrolytes. In this article, we discuss some features and historical developments of Ghosh’s theory to commemorate its centenary year.
Subscription
Login to verify subscription
User
Font Size
Information
- J. C. Ghosh, Chem. Soc. J., 113, 449; 627; 707; 790 (1918).
- S. Arrhenius, Z. Phys. Chem., 1, 481; 631 (1887).
- W. Ostwald, Z. Phys. Chem., 2, 36; 270 (1888).
- N. Bjerrum, Proc. Seventh International Congress of Applied Chemistry, Section X, pp. 55-60, London, 1909.
- J. H. Wolfenden, Ambix, 19, 175 (1972).
- G. N. Lewis and M. Randall, Thermodynamics, McGraw Hill, N.Y. 1923.
- K. Bhattacharyya, IJHS, 49. 4, 371 (2014).
- N. R. Dhar, Nature, 183, 645 (1959).
- W. Sutherland, Phil. Mag., 3, 161 (1902).
- W. Sutherland, Phil. Mag., 12, 1 (1906).
- S. R. Milner, Phil. Mag., 25, 742 (1913).
- J. Walker, Introduction to Physical Chemistry, 9th ed., London, 1922, 262.
- H. J. S. Sand, Trans. Faraday Soc., 15, 172 (1919).
- J. R. Partington, Trans. Faraday Soc., 15, 162 (1919).
- J. C. Ghosh, Trans. Faraday Soc., 15, 154 (1919-20).
- C. A. Krauss, J. Amer. Chem. Soc., 43, 2514(1921).
- J. Kendall, J. Amer. Chem. Soc., 44, 717 (1922).
- P. J. Debye and E. Huckel, Z. Phys., 24, 185; 305 (1923).
- A. Karachalios, Erich Huckel (1896-1980): Physics to Quantum Chemistry (trans. by A. M. Hentschel) Springer, N.Y. 2010.
- N. Ise and I. S. Sagami, Structure Formation in Solution : Ionic Polymer and Colloid particles, Springer, Berlin 2005.
- A. Chagnes, B. Carre, P. Willmann and D. Lamordant, Electrochim. Acta 46, 1783 (2001).
- E. Moggia, Fluid Phase Equilibria, 427, 231 (2016).
- H. Ozaki, K. Kuratani, H. Sano, and T. Kiyobayashi, J. Chem. Phys., 147, 034904 (2017). crossref PMid:28734311
- J. E. Desnoyers and B. E. Conway, J. Phys. Chem, 68, 2305 (1964). https://doi.org/10.1021/j100790a047
- L. M. Varela, J. Carrete, M. García, J. R. Rodríguez, L. J. Gallego, M. Turmine and O. Cabeza, in Ionic Liquids: Theory, Properties, New Approaches, Prof. Alexander Kokorin (Ed.), ISBN: 978-953-307-349-1, InTech, Available from: crossref theory-properties-new-approaches/pseudolatticetheory-of-ionic-liquids.
- L. W. Bahe, J. Phys. Chem., 76, 1062 (1972).
- E. Rilo; M. Dominguez-Perez; L. M. Varela and O. Cabeza, J. Chem. Thermodyn., 54, 68 (2012).
- R. A. Robinson and R. H. Stokes, Electrolyte Solutions, Butterworths, London, 1955.
- P. van Rysselberghe, J. Chem. Phys. 1, 205 (1933).
- H. A. Kramers, Proc. Roy. Acad. Amsterdam, 30, 145 (1927).
- B. N. Ghosh, J. Ind. Chem. Soc., 63, 390 (1986).
- B. N. Ghosh, J. Ind. Chem. Soc., 60, 141
- (1983).
- B. N. Ghosh, J. Ind. Chem. Soc., 61, 213; 420 (1984).
- B. N. Ghosh, J. Ind. Chem. Soc., 62, 189; 855 (1985).
- B. N. Ghosh, J. Ind. Chem. Soc., 57, 398 (1980).
- J. B. Conant, Science and Common Sense, Yale Univ. Press, New Haven, 1951, p 173.
Abstract Views: 388
PDF Views: 16