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One Hundred Years of Ghosh’s Strong Electrolyte Theory
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Abnormal behaviour of strong electrolytes was a hot research topic around the turn of twentieth century. In 1918, J. C. Ghosh published a series of articles dealing with this abnormal behaviour and suggested a cube ischolar_main law for data correlation. The publications were both praised and criticised. Debye and Huckel published in 1923 their well-known theory of strong electrolytes, the square ischolar_main law, which completely overshadowed Ghosh’s theory. By the middle of twentieth century, however, Ghosh’s theory became prominent again, particularly for concentrated electrolyte solutions, in the light of pseudo-lattice theory of strong electrolytes. In this article, we discuss some features and historical developments of Ghosh’s theory to commemorate its centenary year.
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- J. C. Ghosh, Chem. Soc. J., 113, 449; 627; 707; 790 (1918).
- S. Arrhenius, Z. Phys. Chem., 1, 481; 631 (1887).
- W. Ostwald, Z. Phys. Chem., 2, 36; 270 (1888).
- N. Bjerrum, Proc. Seventh International Congress of Applied Chemistry, Section X, pp. 55-60, London, 1909.
- J. H. Wolfenden, Ambix, 19, 175 (1972).
- G. N. Lewis and M. Randall, Thermodynamics, McGraw Hill, N.Y. 1923.
- K. Bhattacharyya, IJHS, 49. 4, 371 (2014).
- N. R. Dhar, Nature, 183, 645 (1959).
- W. Sutherland, Phil. Mag., 3, 161 (1902).
- W. Sutherland, Phil. Mag., 12, 1 (1906).
- S. R. Milner, Phil. Mag., 25, 742 (1913).
- J. Walker, Introduction to Physical Chemistry, 9th ed., London, 1922, 262.
- H. J. S. Sand, Trans. Faraday Soc., 15, 172 (1919).
- J. R. Partington, Trans. Faraday Soc., 15, 162 (1919).
- J. C. Ghosh, Trans. Faraday Soc., 15, 154 (1919-20).
- C. A. Krauss, J. Amer. Chem. Soc., 43, 2514(1921).
- J. Kendall, J. Amer. Chem. Soc., 44, 717 (1922).
- P. J. Debye and E. Huckel, Z. Phys., 24, 185; 305 (1923).
- A. Karachalios, Erich Huckel (1896-1980): Physics to Quantum Chemistry (trans. by A. M. Hentschel) Springer, N.Y. 2010.
- N. Ise and I. S. Sagami, Structure Formation in Solution : Ionic Polymer and Colloid particles, Springer, Berlin 2005.
- A. Chagnes, B. Carre, P. Willmann and D. Lamordant, Electrochim. Acta 46, 1783 (2001).
- E. Moggia, Fluid Phase Equilibria, 427, 231 (2016).
- H. Ozaki, K. Kuratani, H. Sano, and T. Kiyobayashi, J. Chem. Phys., 147, 034904 (2017). crossref PMid:28734311
- J. E. Desnoyers and B. E. Conway, J. Phys. Chem, 68, 2305 (1964). https://doi.org/10.1021/j100790a047
- L. M. Varela, J. Carrete, M. García, J. R. Rodríguez, L. J. Gallego, M. Turmine and O. Cabeza, in Ionic Liquids: Theory, Properties, New Approaches, Prof. Alexander Kokorin (Ed.), ISBN: 978-953-307-349-1, InTech, Available from: crossref theory-properties-new-approaches/pseudolatticetheory-of-ionic-liquids.
- L. W. Bahe, J. Phys. Chem., 76, 1062 (1972).
- E. Rilo; M. Dominguez-Perez; L. M. Varela and O. Cabeza, J. Chem. Thermodyn., 54, 68 (2012).
- R. A. Robinson and R. H. Stokes, Electrolyte Solutions, Butterworths, London, 1955.
- P. van Rysselberghe, J. Chem. Phys. 1, 205 (1933).
- H. A. Kramers, Proc. Roy. Acad. Amsterdam, 30, 145 (1927).
- B. N. Ghosh, J. Ind. Chem. Soc., 63, 390 (1986).
- B. N. Ghosh, J. Ind. Chem. Soc., 60, 141
- (1983).
- B. N. Ghosh, J. Ind. Chem. Soc., 61, 213; 420 (1984).
- B. N. Ghosh, J. Ind. Chem. Soc., 62, 189; 855 (1985).
- B. N. Ghosh, J. Ind. Chem. Soc., 57, 398 (1980).
- J. B. Conant, Science and Common Sense, Yale Univ. Press, New Haven, 1951, p 173.
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