Journal of Surface Science and Technology

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Mixed Micelle Properties of Anionic Dimeric Surfactants with Anionic, Cationic, and Nonionic Surfactants


Affiliations
1 Department of Chemistry, Shobhit University, Gangoh, Saharanpur - 247341, Uttar Pradesh, India
2 Department of Chemistry, Jaypee University of Engineering & Technology, Guna - 473226, Madhya Pradesh, India
     

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Herein, we have investigated the mixed micellar behavior of carboxylate anionic dimeric surfactants (CAD12 and CAD16) with commercial surfactants; anionic type i.e., sodium dodecyl sulfate, cationic i.e., cetyltrimethylammonium bromide and nonionic i.e., polyethylene glycol p-(1,1,3,3-tetramethylbutyl)-phenyl ether. The CMC values of mixed surfactants obtained from conductivity data decrease with a mole fraction of dimeric surfactants. The micellar characteristics (ideal CMC) and mutual interaction parameters (β) have been computed with the aid of theoretical models proposed by Clint, and Rubingh. In addition to this, thermodynamic parameters of micellization like ∆Gmic0, ∆Hmic0 , and ∆Smic0 were evaluated and discussed.

Keywords

Conventional Surfactants, Critical Micelle Concentration, Dimeric Surfactants, Interaction Parameter, Mixed Micellization.
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  • Y. Zheng, X. Lu, L. Lai, L. Yu, H. Zheng, C. Dai, J. of Molecular Liquids, 299, 112108 (2020). https://doi.org/10.1016/j.mol-liq.2019.112108.

  • N. Kumar, R. Tyagi, J. Dispers. Sci. Technol., 36, 1601 (2015). https://doi.org/10.1080/01932691.2014.981339.

  • A.R. Malik, A. Abdulrahman, A. Naved, M.A. Abdullah, J. of Molecular Liquids, 311, 113 (2020).

  • A. McLachlan, K. Singh, M. McAlduff, D.G. Marangoni, S. Shortall, S.D. Wettig, RSC Adv., 10, 3221 (2020). https://doi.org/10.1039/C9RA09432F. PMid:35497753 PMCid:PMC9049202.

  • S. Ghosh, A. Mal, T. Chakraborty, G. Chandra De, D.G. Marangoni, J. of Surface Science and Technology, 32, 14746 (2016). https://doi.org/10.18311/jsst/2016/6572,

  • L. Berriche, L. Badache, S.H. Ben Hariz, A. Gharbi, W. Talhi, J. of Dispersion Science and Technology, 40, 378 (2019). https://doi.org/10.1080/01932691.2018.1470010.

  • A.K. Sood, H. Kaur, T.S. Banipal, Arabian Journal of Chemistry, 12, 3847 (2019). https://doi.org/10.1016/j.arabjc.2015.12.009.

  • I.H. Ali, S.H. Kareem, J. of Surface Science and Technology, 35, 21455 (2019).

  • A. Shiloach, D. Blankschtein, Langmuir, 14, 1618 (1998). https://doi.org/10.1021/la971151r.

  • S.K. Hait, S.P. Moulik, Current Science, 82, 1101 (2002).

  • N. Kumar, R. Tyagi, Tenside Surf. Det., 56, 172 (2019). https://doi.org/10.3139/113.110614.

  • N. Kumar, R. Tyagi, J. of Dispersion Science and Technology, 35, 205 (2014). https://doi.org/10.1080/01932691.2013.780 243.

  • N. Kumar, R. Tyagi, Cosmetics, 1, 3 (2014). https://doi.org/10.3390/cosmetics1010003.

  • D. Tikariha, K.K. Ghosh, P. Quagliotto, S. Ghosh, Chem. Eng. Data, 55, 4162 (2010). https://doi.org/10.1021/je100113r.

  • N. Azum, M. Abdul Rub, A. Khan, M.M. Alotaibi, A.M. Asiri, M. Rahman, Gels, 8, 128 (2022). https://doi.org/10.3390/gels8020128. PMid:35200509 PMCid:PMC8872345.

  • P. Sharma, S. Sachar, G. Kaur, P. Thakur, M.S. Bakshi, T.S. Banipal, J. of Surface Science and Technology, 23, 131 (2007).

  • T. Chakraborty, S. Ghosh, Colloid Poly. Sci., 285, 1665 (2007). https://doi.org/10.1007/s00396-007-1738-1.

  • N. Kumar, R. Tyagi, Int. J. Ind. Chem., 6, 59 (2015). https://doi.org/10.1007/s40090-015-0032-1.

  • N. Kumar, R. Tyagi, J. of Taibah University for Sci., 9, 69 (2015). https://doi.org/10.1016/j.jtusci.2014.06.005.

  • A.E. Bailey, Bailey’s Industrial Oil and Fat Products, 5th ed.; Wiley, New York (1995).

  • P.S. Niranjan, S.K. Upadhyay, J. of Dispersion Science and Tech., 32, 109 (2010). https://doi.org/10.1080/01932690903542982.

  • A. Modaressi, H. Sifaoui, B. Grzesiak, R. Solimando, U. Domanskac, M. Rogalski, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 296, 104 (2007). https://doi.org/10.1016/j.colsurfa.2006.09.031.

  • C.C. Ruiz, J.A. Molina-Bolivar, J. Aguiar, Langmuir, 17, 6831 (2001). https://doi.org/10.1021/la010529p.

  • S. Ghosh, T. Chakraborty, J. of Physical Chem. B, 111, 8080 (2007). https://doi.org/10.1021/jp067761u. PMid:17530882.

  • J.H. Clint, Surfactant Aggregation; Blackie, Chapman & Hall, New York, (1992). https://doi.org/10.1007/978-94-011-2272-6.

  • J.H. Clint, J. of the Chemical Society, Faraday Transactions, 1, 1327 (1975). https://doi.org/10.1039/f19757101327.

  • D.N. Rubingh, Solution Chemistry of Surfactants; In: Mittal KL (ed) Plenum Press, New York, (1979).

  • N. Azum, A.Z. Naqvi, M. Akram, Kabir-ud-Din, J. of Dispersion Science and Technology, 29, 711 (2008). https://doi.org/10.1080/01932690701756735.

  • M.S. Bakshi, K. Singh, Journal of Colloid and Interface Sci., 287, 288 (2005). https://doi.org/10.1016/j.jcis.2005.01.099. PMid:15914176.

  • A.Z. Naqvi, Kabir-ud-Din, M. Panda, Journal of Molecular Liquids, 343, 116876 (2021). https://doi.org/10.1016/j.mol-liq.2021.116876.

  • H. Maeda, J. of Colloid and Interface Sci., 172, 98 (1995). https://doi.org/10.1006/jcis.1995.1230.

  • M.S. Bakshi, J. Singh, K. Singh, G. Kaur, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 237, 61 (2004). https://doi.org/10.1016/j.colsurfa.2004.01.030.

  • X. Wang, J. Wang, Y. Wang, J. Ye, H. Yan, R.K. Thomas, J Colloid Interface Sci., 15, 739 (2005). https://doi.org/10.1016/j.jcis.2005.01.084. PMid:15897092

  • A.Z. Naqvi, S. Noori, Kabir-ud-Din, RSC Advances, 6, 20324 (2016). https://doi.org/10.1039/C5RA24058A.

  • R. Patel, A.B. Khan, N. Dohare, M.M. Ali, H.K. Rajor, J.Surfact Deterg., 18, 719 (2015). https://doi.org/10.1007/s11743-015-1709-3


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  • Mixed Micelle Properties of Anionic Dimeric Surfactants with Anionic, Cationic, and Nonionic Surfactants

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Authors

Naveen Kumar
Department of Chemistry, Shobhit University, Gangoh, Saharanpur - 247341, Uttar Pradesh, India
Rashmi Tyagi
Department of Chemistry, Jaypee University of Engineering & Technology, Guna - 473226, Madhya Pradesh, India

Abstract


Herein, we have investigated the mixed micellar behavior of carboxylate anionic dimeric surfactants (CAD12 and CAD16) with commercial surfactants; anionic type i.e., sodium dodecyl sulfate, cationic i.e., cetyltrimethylammonium bromide and nonionic i.e., polyethylene glycol p-(1,1,3,3-tetramethylbutyl)-phenyl ether. The CMC values of mixed surfactants obtained from conductivity data decrease with a mole fraction of dimeric surfactants. The micellar characteristics (ideal CMC) and mutual interaction parameters (β) have been computed with the aid of theoretical models proposed by Clint, and Rubingh. In addition to this, thermodynamic parameters of micellization like ∆Gmic0, ∆Hmic0 , and ∆Smic0 were evaluated and discussed.

Keywords


Conventional Surfactants, Critical Micelle Concentration, Dimeric Surfactants, Interaction Parameter, Mixed Micellization.

References